Cooperative catalytic platinum species accelerating polysulfide redox reactions for Li-S batteries

doi:10.1016/j.jechem.2023.08.015

IMR OpenIR

	Cooperative catalytic platinum species accelerating polysulfide redox reactions for Li-S batteries
	Qi, Yujie 1,2; Chai, Ning 1,3; Gu, Qinhua 1,2; Chen, Junnan 1,2; Zhai, Zhaofeng 1,2; Lu, Ming 1,4; Niu, Yiming 1,2; Huang, Nan 1,2; Zhang, Xia 3; Zhang, Bingsen 1,2
通讯作者	Huang, Nan(nhuang@imr.ac.cn) ; Zhang, Xia(xzhang@mail.neu.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn)
	2023-12-01
发表期刊	JOURNAL OF ENERGY CHEMISTRY
ISSN	2095-4956
卷号	87 页码:123-135
摘要	The shuttle effect derived from diffusion of lithium polysulfides (LiPSs) and sluggish redox kinetic bring about poor cycling stability and low utilization of sulfur, which have always been the key challenging issues for the commercial application of lithium-sulfur (Li-S) batteries. Rational design of cathode materials to catalyze Li2S dissociation/nucleation processes is an appealing and valid strategy to develop high-energy practical Li-S batteries. Herein, considering the synergistic effect of bidirectional catalysis on LiPSs conversion and enhanced chemical immobilization for LiPSs by heteroatom doping, Pt nanoparticles loaded on nitrogen-doped carbon spheres (Pt/NCS composites) were constructed as cathode materials. According to the dynamic evolution of Pt catalysts and sulfur species, Pt0 and Pt2+ species were identified as active species for the accelerated dissociation and nucleation of Li2S, respectively. Meanwhile, in-situ Raman results demonstrated the expedited conversion of sulfur species resulted from bidirectional catalysis of active Pt species, corresponding to boosted redox kinetics. Consequently, Pt/NCS cathode exhibited improved long-term cyclability with high initial capacity, along with enhanced rate capability. This work provides a facile approach to construct cathode materials with bidirectional catalysis on Li2S dissociation/ nucleation, and sheds light on a more global understanding of the catalytic mechanism of metal catalysts during LiPSs conversion.(c) 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.
关键词	Lithium-sulfur batteries Platinum species N -doped carbon spheres Bidirectional catalysis Polysulfide conversion
资助者	National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Research Fund of Shenyang National Laboratory for Materials Science ; Natural Science Foundation of Liaoning Province ; Science and Technology Research Project of Education Department of Jilin Province ; IMR Innovation Fund
DOI	10.1016/j.jechem.2023.08.015
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51932005] ; National Natural Science Foundation of China[22072164] ; Liaoning Revitalization Talents Program[XLYC1807175] ; Research Fund of Shenyang National Laboratory for Materials Science ; Natural Science Foundation of Liaoning Province[JJKH20210453KJ] ; Science and Technology Research Project of Education Department of Jilin Province[2023-PY10] ; IMR Innovation Fund ; [2023-BS-013]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:001081721100001
出版者	ELSEVIER
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/179455
专题	中国科学院金属研究所
通讯作者	Huang, Nan; Zhang, Xia; Zhang, Bingsen
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 3.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Liaoning, Peoples R China 4.Jilin Normal Univ, Minist Educ, Key Lab Funct Mat Phys & Chem,Joint Lab MXene Mat, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Peoples R China
推荐引用方式 GB/T 7714	Qi, Yujie,Chai, Ning,Gu, Qinhua,et al. Cooperative catalytic platinum species accelerating polysulfide redox reactions for Li-S batteries[J]. JOURNAL OF ENERGY CHEMISTRY,2023,87:123-135.
APA	Qi, Yujie.,Chai, Ning.,Gu, Qinhua.,Chen, Junnan.,Zhai, Zhaofeng.,...&Zhang, Bingsen.(2023).Cooperative catalytic platinum species accelerating polysulfide redox reactions for Li-S batteries.JOURNAL OF ENERGY CHEMISTRY,87,123-135.
MLA	Qi, Yujie,et al."Cooperative catalytic platinum species accelerating polysulfide redox reactions for Li-S batteries".JOURNAL OF ENERGY CHEMISTRY 87(2023):123-135.