Electrocatalytic CO2 reduction for the selective production of liquid

doi:10.1016/j.jechem.2024.12.022

IMR OpenIR

	Electrocatalytic CO2 reduction for the selective production of liquid
	Ji, Jiapeng 1; Chen, Junnan 1; Xiong, Juxia 1; Zhang, Xiaolong 1,2; Cheng, Hui-Ming 1,2,3
通讯作者	Zhang, Xiaolong(xl.zhang@siat.ac.cn) ; Cheng, Hui-Ming(hm.cheng@siat.ac.cn)
	2025-04-01
发表期刊	JOURNAL OF ENERGY CHEMISTRY
ISSN	2095-4956
卷号	103 页码:568-600
摘要	Electrocatalytic CO2 reduction (ECR) to produce value-added fuels and chemicals using renewable electricity is an emerging strategy to mitigate global warming and decrease reliance on fossil fuels. Among various ECR products, liquid oxygenates (Oxys) are especially attractive due to their high energy density, high safety and transportability that could be adapted to the existing infrastructure and transportation system. However, efficiently generating these highly reduced oxygen-containing products by ECR remains challenging due to the complexity of coupled proton and electron transfer processes. In recent years, in-depth studies of reaction mechanisms have advanced the design of catalysts and the regulation of reaction systems for ECR to produce Oxys. Here, by focusing on the production of typical Oxys, such as methanol, acetic acid, ethanol, acetone, n-propanol, and isopropanol, we outline various reaction paths and key intermediates for the electrochemical conversion of CO2 into these target products. We also summarize the current research status and recent advances in catalysts based on their elemental composition, and consider recent studies on the change of catalyst geometry and electronic structure, as well as the optimization of reaction systems to increase ECR performance. Finally, we analyze the challenges in the field of ECR to Oxys and provide an outlook on future directions for high-efficiency catalyst prediction and design, as well as the development of advanced reaction systems. (c) 2024 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights are reserved, including those for text and data mining, AI training, and similar technologies.
关键词	Electrocatalytic CO2 reduction Geometry and electronic structure Parameters and system configurations Liquid oxygenates
资助者	National Natural Science Foundation of China ; Talent Introduction Project of Chinese Academy of Sciences ; Shenzhen High Level Talent Team Project ; Joint Research Project of China Merchants Group and SIAT ; Cross Institute Joint Research Youth Team Project of SIAT ; National Natural Science Foundation of China ; China Postdoctoral Science Foundation
DOI	10.1016/j.jechem.2024.12.022
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52201237] ; Talent Introduction Project of Chinese Academy of Sciences[E344011] ; Shenzhen High Level Talent Team Project[KQTD2022110109364705] ; Joint Research Project of China Merchants Group and SIAT[E2Z1521] ; Cross Institute Joint Research Youth Team Project of SIAT[E25427] ; National Natural Science Foundation of China[52402136] ; China Postdoctoral Science Foundation[E325281005]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:001398813100001
出版者	ELSEVIER
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/180247
专题	中国科学院金属研究所
通讯作者	Zhang, Xiaolong; Cheng, Hui-Ming
作者单位	1.Chinese Acad Sci, Inst Technol Carbon Neutral, Shenzhen Inst Adv Technol, Shenzhen Key Lab Energy Mat Carbon Neutral, Shenzhen 518055, Guangdong, Peoples R China 2.Shenzhen Univ Adv Technol, Fac Mat Sci & Energy Engn, Shenzhen 518055, Guangdong, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Ji, Jiapeng,Chen, Junnan,Xiong, Juxia,et al. Electrocatalytic CO2 reduction for the selective production of liquid[J]. JOURNAL OF ENERGY CHEMISTRY,2025,103:568-600.
APA	Ji, Jiapeng,Chen, Junnan,Xiong, Juxia,Zhang, Xiaolong,&Cheng, Hui-Ming.(2025).Electrocatalytic CO2 reduction for the selective production of liquid.JOURNAL OF ENERGY CHEMISTRY,103,568-600.
MLA	Ji, Jiapeng,et al."Electrocatalytic CO2 reduction for the selective production of liquid".JOURNAL OF ENERGY CHEMISTRY 103(2025):568-600.