Simultaneous improvement of wear and corrosion resistance of microarc oxidation coatings on ZK61 Mg alloy by doping with ZrO2 nanoparticles

doi:10.1016/j.jmst.2024.10.023

IMR OpenIR

	Simultaneous improvement of wear and corrosion resistance of microarc oxidation coatings on ZK61 Mg alloy by doping with ZrO2 nanoparticles
	Yang, Chao 1,2; Wang, Chenyu 1,2; Shen, Zhao 1,2,3; Zhou, Liping 1,2; Sheng, Liyuan 4,5; Xu, Daokui 6; Zheng, Yufeng 4; Chu, Paul K.7,8; Xiao, Shu 9; Ying, Tao 1,2; Zeng, Xiaoqin 1,2
通讯作者	Shen, Zhao(shenzhao081@sjtu.edu.cn) ; Sheng, Liyuan(lysheng@yeah.net) ; Xiao, Shu(xiaos@scut.edu.cn)
	2025-07-20
发表期刊	JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN	1005-0302
卷号	224 页码:312-327
摘要	The poor corrosion resistance of magnesium (Mg) and its alloys limits their application in various fields. Micro arc oxidation (MAO) coatings can improve the corrosion resistance, but the pore defects and low surface hardness make them susceptible to wear and accelerated corrosion during usage. In this study, a ZrO2 nanoparticles doped-MAO coating is prepared on the ZK61 Mg alloy by utilizing an MgF2 passivation layer to prevent ablation. The ZrO2 nanoparticles re-melt and precipitate due to local discharging, which produces evenly dispersed nanocrystals in the MAO coating. As a result, the hardness of the MAO coating with the appropriate ZrO2 concentration increases by over 10 times, while the wear rate decreases and corrosion resistance increases. With increasing ZrO2 concentrations, the corrosion potentials increase from -1.528 V of the bare ZK61 Mg alloy to -1.184 V, the corrosion current density decreases from 1.065 x 10-4 A cm-2 to 3.960 x 10-8 A cm-2 , and the charge transfer resistance increases from 3.41 x 102 Q cm2 to 6.782 x 105 5 cm2 . Immersion tests conducted in a salt solution for 28 d reveal minimal corrosion in contrast to severe corrosion on the untreated ZK61 Mg alloy. ZrO2 nanoparticles improve the corrosion resistance of MAO coatings by sealing pores and secondary strengthening of the corrosion product layer. (c) 2025 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
关键词	ZK61 Mg alloy Micro arc oxidation ZrO 2 doping MgF2 Wear resistance Corrosion resistance
资助者	Shanghai Post-doctoral Excellence Program ; National Natural Science Foundation of China ; Shenzhen Basic Research Project ; Guangdong Basic and Applied Basic Research Foundation ; IER Foundation ; City University of Hong Kong Donation Research ; Hong Kong PDFS-RGC Postdoctoral Fellowship Scheme ; Hong Kong HMRF (Health and Medi-cal Research Fund)
DOI	10.1016/j.jmst.2024.10.023
收录类别	SCI
语种	英语
资助项目	Shanghai Post-doctoral Excellence Program[2023440] ; National Natural Science Foundation of China[52127801] ; National Natural Science Foundation of China[52401101] ; National Natural Science Foundation of China[22205012] ; Shenzhen Basic Research Project[JCYJ20210324120001003] ; Shenzhen Basic Research Project[JCYJ20200109144608205] ; Guangdong Basic and Applied Basic Research Foundation[2020A1515011301] ; Guangdong Basic and Applied Basic Research Foundation[2021A1515012246] ; IER Foundation[IERF202201] ; IER Foundation[IERF202202] ; City University of Hong Kong Donation Research[DON-RMG 9229021] ; Hong Kong PDFS-RGC Postdoctoral Fellowship Scheme[PDFS2122-1S08] ; Hong Kong PDFS-RGC Postdoctoral Fellowship Scheme[CityU 9061014] ; Hong Kong HMRF (Health and Medi-cal Research Fund)[2120972] ; Hong Kong HMRF (Health and Medi-cal Research Fund)[CityU 9211320]
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:001405504800001
出版者	ELSEVIER
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/180325
专题	中国科学院金属研究所
通讯作者	Shen, Zhao; Sheng, Liyuan; Xiao, Shu
作者单位	1.Shanghai Jiao Tong Univ, Natl Engn Res Ctr Light Alloy Net Forming, Shanghai 200240, Peoples R China 2.Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China 3.Shanghai Jiao Tong Univ, Inst & Med Robot, Shanghai 200240, Peoples R China 4.Peking Univ, Shenzhen Inst, Shenzhen 518057, Peoples R China 5.PKU HKUST Shenzhen Hong Kong Inst, Shenzhen 518057, Peoples R China 6.Chinese Acad Sci, Key Lab Nucl Mat & Safety Assessment, Inst Met Res, Shenyang 110016, Peoples R China 7.City Univ Hong Kong, Dept Phys, Dept Mat Sci & Engn, Kowloon, Tat Chee Ave, Hong Kong 999077, Peoples R China 8.City Univ Hong Kong, Dept Biomed Engn, Kowloon, Tat Chee Ave, Hong Kong 999077, Peoples R China 9.South China Univ Technol, Sch Mech & Automot Engn, Guangzhou 510641, Peoples R China
推荐引用方式 GB/T 7714	Yang, Chao,Wang, Chenyu,Shen, Zhao,et al. Simultaneous improvement of wear and corrosion resistance of microarc oxidation coatings on ZK61 Mg alloy by doping with ZrO2 nanoparticles[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2025,224:312-327.
APA	Yang, Chao.,Wang, Chenyu.,Shen, Zhao.,Zhou, Liping.,Sheng, Liyuan.,...&Zeng, Xiaoqin.(2025).Simultaneous improvement of wear and corrosion resistance of microarc oxidation coatings on ZK61 Mg alloy by doping with ZrO2 nanoparticles.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,224,312-327.
MLA	Yang, Chao,et al."Simultaneous improvement of wear and corrosion resistance of microarc oxidation coatings on ZK61 Mg alloy by doping with ZrO2 nanoparticles".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 224(2025):312-327.