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Study on deposition of biomedical Ta coating on Ti6Al4V alloy substrate by CVD and its properties
Liu, Fan1,2; Wang, Huyue1,3; Zhao, Bo1,3; Zhang, Wei5,6; Wang, Qiang5,6; Niu, Yunsong1; Wang, Yu4; Yu, Hailong4; Wang, Qingchuan1; Yang, Ke1
通讯作者Wang, Yu(wangyu1983doc@qq.com) ; Yu, Hailong(yuhailong118@aliyun.com) ; Wang, Qingchuan(qcwang11s@imr.ac.cn)
2025
发表期刊SURFACE & COATINGS TECHNOLOGY
ISSN0257-8972
卷号495页码:10
摘要With superior bone growth and integration abilities, porous tantalum (Ta) implants prepared by depositing Ta coating on foam carbon have been widely used in clinical for two decades. To solve their high cost and high weight disadvantages, the deposition of thin Ta coating on porous titanium (Ti) alloys substrate by chemical vapor deposition (CVD) is expected to be a promising strategy. However, until now realizing the novel strategy is still a big challenge. In this study, by the TaCl5-H2 reaction, we investigated the preparation of Ta coating on Ti6Al4V (TC4) matrix by CVD. The effects of reaction temperature and gas flow on the microstructure, composition, and properties of the Ta coating were systematically investigated. The results indicated that Ta coatings about 5 mu m with high quality was successfully prepared on plane and porous TC4 for the first time, and the reaction temperature played a more important role than the gas flow. The optimal preparation parameters were determined to be 950 degrees C and 200 sccm. Under the condition, Ta coating with the fully alpha-Ta phase, high purity, high uniformity and compactness was achieved. The Ta coating exhibited excellent binding force, corrosion resistance, hydrophilicity. Through eliminating the toxic V ions dissolution from TC4, the Ta coating also obtained excellent cell compatibility, which is meaningful for porous TC4 implants widely used in clinic with very high specific surface area. Therefore, this research evidenced that, by CVD, the novel thin Ta coated porous TC4 implants with lower cost, lower weight and higher biocompatibility could be achieved.
关键词Ta coating CVD Biomedical Ti6Al4V Corrosion resistance
资助者National Key Research and Devel-opment Program of China ; Liaoning Province Science and Technology Plan Joint Program
DOI10.1016/j.surfcoat.2024.131593
收录类别SCI
语种英语
资助项目National Key Research and Devel-opment Program of China[2023YFC2507604] ; National Key Research and Devel-opment Program of China[2020YFC1107501] ; Liaoning Province Science and Technology Plan Joint Program[2023021005-JH2/1017]
WOS研究方向Materials Science ; Physics
WOS类目Materials Science, Coatings & Films ; Physics, Applied
WOS记录号WOS:001367127700001
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/181534
专题中国科学院金属研究所
通讯作者Wang, Yu; Yu, Hailong; Wang, Qingchuan
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
3.Northeastern Univ, Sch Mat Sci & Engn, Shenyang 110819, Peoples R China
4.Gen Hosp Northern Theater Command, Shenyang 110000, Peoples R China
5.China Med Univ, Sch & Hosp Stomatol, Shenyang 110001, Peoples R China
6.Liaoning Prov Key Lab Oral Dis, Shenyang 110001, Peoples R China
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GB/T 7714
Liu, Fan,Wang, Huyue,Zhao, Bo,et al. Study on deposition of biomedical Ta coating on Ti6Al4V alloy substrate by CVD and its properties[J]. SURFACE & COATINGS TECHNOLOGY,2025,495:10.
APA Liu, Fan.,Wang, Huyue.,Zhao, Bo.,Zhang, Wei.,Wang, Qiang.,...&Yang, Ke.(2025).Study on deposition of biomedical Ta coating on Ti6Al4V alloy substrate by CVD and its properties.SURFACE & COATINGS TECHNOLOGY,495,10.
MLA Liu, Fan,et al."Study on deposition of biomedical Ta coating on Ti6Al4V alloy substrate by CVD and its properties".SURFACE & COATINGS TECHNOLOGY 495(2025):10.
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