Mechanochemical activation of 2D MnPS<sub>3</sub> for sub-attomolar sensing

doi:10.1038/s41467-024-54608-0

IMR OpenIR

	Mechanochemical activation of 2D MnPS₃ for sub-attomolar sensing
	Chen, Wenjun 1; Gui, Jiabao 1; Weng, Xiangchao 1; Tan, Junyang 2,3; Huang, Junhua 4; Lin, Zhiqiang 5; Zhao, Benli 6,7; Wang, Lang-Hong 8; Zeng, Xin-An 8; Teng, Changjiu 1; Zhao, Shilong 1; Ding, Baofu 9; Liu, Bilu 2,3; Cheng, Hui-Ming 9,10,11,12
通讯作者	Chen, Wenjun(chenwj46@fosu.edu.cn) ; Teng, Changjiu(cjteng@fosu.edu.cn) ; Zhao, Shilong(shilongzhao@fosu.edu.cn) ; Cheng, Hui-Ming(hm.cheng@siat.ac.cn)
	2024-11-25
发表期刊	NATURE COMMUNICATIONS
卷号	15 期号:1 页码:9
摘要	Molecular detection is important in biosensing, food safety, and environmental surveillance. The high biocompatibility, superior mechanical stability, and low cost make plasmon-free surface-enhanced Raman scattering (SERS) a promising sensing technique, the ultrahigh sensitivity of which is urgently pursued for realistic applications. As a proof of concept, we report a mechanochemical strategy, which combines the wrinkling and chemical functionalization, to fabricate a plasmon-free SERS platform based on 2D MnPS3 with a sub-attomolar detection limit. In detail, the formation of wrinkles in 2D MnPS3 enables a SERS substrate of the material to detect trace methylene blue molecules. The mechanism is experimentally revealed that the wrinkled structures contribute to the improvement of light-matter coupling. On this basis, decorating a wrinkled MnPS3 which has absorbed methylene blue with histamine dihydrochloride further lowers the detection limit to 10-19 M. Because the amino groups in histamine dihydrochloride molecules are crosslinkers that create more pathways to promote charge transfer between these substances. This work provides a guidance for the design of SERS sensors with single-molecule-level sensitivity. Here, the authors develop a plasmon-free SERS platform based on two-dimensional MnPS3 with sub-attomolar detection limit. Their strategy is based on a mechanochemical approach that combines wrinkling and chemical functionalization to boost SERS performance, making it relevant for biosensing.
资助者	National Natural Science Foundation of China (National Science Foundation of China) ; Guangdong Basic and Applied Basic Research Foundation ; National Natural Science Foundation of China ; National Science Fund for Distinguished Young Scholars ; Shenzhen Basic Research Program ; Guangdong Research Fund ; Tsinghua Shenzhen International Graduate School (Tsinghua SIGS)
DOI	10.1038/s41467-024-54608-0
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China (National Science Foundation of China)[2022A1515140158] ; National Natural Science Foundation of China (National Science Foundation of China)[2023A1515110759] ; National Natural Science Foundation of China (National Science Foundation of China)[2023A1515011752] ; Guangdong Basic and Applied Basic Research Foundation[51991343] ; Guangdong Basic and Applied Basic Research Foundation[51991340] ; Guangdong Basic and Applied Basic Research Foundation[52102179] ; Guangdong Basic and Applied Basic Research Foundation[52188101] ; Guangdong Basic and Applied Basic Research Foundation[12304212] ; National Natural Science Foundation of China[52125309] ; National Science Fund for Distinguished Young Scholars[JCYJ20200109144616617] ; National Science Fund for Distinguished Young Scholars[JCYJ20220818101014029] ; Shenzhen Basic Research Program[2024LH7-3] ; Guangdong Research Fund ; Tsinghua Shenzhen International Graduate School (Tsinghua SIGS)
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:001364059600004
出版者	NATURE PORTFOLIO
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/181562
专题	中国科学院金属研究所
通讯作者	Chen, Wenjun; Teng, Changjiu; Zhao, Shilong; Cheng, Hui-Ming
作者单位	1.Foshan Univ, Sch Elect Informat Engn, Foshan, Peoples R China 2.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen Geim Graphene Ctr, Shenzhen, Peoples R China 3.Tsinghua Univ, Inst Mat Res, Tsinghua Shenzhen Int Grad Sch, Shenzhen, Peoples R China 4.Sun Yat Sen Univ, Sch Elect & Informat Technol, State Key Lab Optoelect Mat & Technol, Guangzhou, Peoples R China 5.Chinese Acad Sci, Shenzhen Inst Adv Elect Mat, Shenzhen Inst Adv Technol, Natl Key Lab Mat Integrated Circuits, Shenzhen, Peoples R China 6.Foshan Univ, Foshan Stomatol Hosp, Foshan, Peoples R China 7.Foshan Univ, Sch Med, Foshan, Peoples R China 8.Foshan Univ, Sch Food Sci & Engn, Guangdong Prov Key Lab Intelligent Food Mfg, Foshan, Peoples R China 9.Chinese Acad Sci, Inst Technol Carbon Neutral, Shenzhen Inst Adv Technol, Fac Mat Sci & Energy Engn, Shenzhen, Peoples R China 10.Shenzhen Inst Adv Technol, Fac Mat Sci & Energy Engn, Shenzhen, Peoples R China 11.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen Key Lab Energy Mat Carbon Neutral, Shenzhen, Peoples R China 12.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China
推荐引用方式 GB/T 7714	Chen, Wenjun,Gui, Jiabao,Weng, Xiangchao,et al. Mechanochemical activation of 2D MnPS₃ for sub-attomolar sensing[J]. NATURE COMMUNICATIONS,2024,15(1):9.
APA	Chen, Wenjun.,Gui, Jiabao.,Weng, Xiangchao.,Tan, Junyang.,Huang, Junhua.,...&Cheng, Hui-Ming.(2024).Mechanochemical activation of 2D MnPS₃ for sub-attomolar sensing.NATURE COMMUNICATIONS,15(1),9.
MLA	Chen, Wenjun,et al."Mechanochemical activation of 2D MnPS₃ for sub-attomolar sensing".NATURE COMMUNICATIONS 15.1(2024):9.