Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis

doi:10.1021/acsnano.3c09806

IMR OpenIR

	Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis
	Li, Feng 1; Yao, Canglang 1; Jeon, Jong-Pil 2; Han, Gao-Feng 2; Shin, Tae Joo 4; Han, Ali 5; Fu, Zhengping 3; Lu, Yalin 3; Baek, Jong-Beom 2
通讯作者	Li, Feng(li_feng@fudan.edu.cn) ; Han, Ali(alhan@imr.ac.cn) ; Baek, Jong-Beom(jbbaek@unist.ac.kr)
	2023-11-27
发表期刊	ACS NANO
ISSN	1936-0851
卷号	17 期号:23 页码:24282-24289
摘要	Efficient and stable catalysts are highly desired for the electrochemical conversion of hydrogen, oxygen, and water molecules, processes which are crucial for renewable energy conversion and storage technologies. Herein, we report the development of hollow nitrogenated carbon sphere (HNC) dispersed rhodium (Rh) single atoms (Rh1HNC) as an efficient catalyst for bifunctional catalysis. The Rh1HNC was achieved by anchoring Rh single atoms in the HNC matrix with an Rh-N3C1 configuration, via a combination of in situ polymerization and carbonization approach. Benefiting from the strong metal atom-support interaction (SMASI), the Rh and C atoms can collaborate to achieve robust electrochemical performance toward both the hydrogen evolution and oxygen reduction reactions in acidic media. This work not only provides an active site with favorable SMASI for bifunctional catalysis but also brings a strategy for the design and synthesis of efficient and stable bifunctional catalysts for diverse applications.
关键词	catalyst active sites electrochemistry hydrogen evolution reaction energy conversion
资助者	Fudan University ; Fudan University ; National Natural Science Foundation of China ; National Research Foundation (NRF) of Korea
DOI	10.1021/acsnano.3c09806
收录类别	SCI
语种	英语
资助项目	Fudan University[JIH2203004Y] ; Fudan University[QXH2203003] ; Fudan University[2014R1A3A2069102] ; National Natural Science Foundation of China ; National Research Foundation (NRF) of Korea
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:001125127900001
出版者	AMER CHEMICAL SOC
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/182889
专题	中国科学院金属研究所
通讯作者	Li, Feng; Han, Ali; Baek, Jong-Beom
作者单位	1.Fudan Univ, Lab Adv Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, Handan 220, Shanghai 200433, Peoples R China 2.Ulsan Natl Inst Sci & Technol UNIST, Ctr Dimens Controllable Organ Frameworks, Sch Energy & Chem Engn, Ulsan 44919, South Korea 3.Univ Sci & Technol China, Anhui Lab Adv Photon Sci & Technol, Hefei 230026, Anhui, Peoples R China 4.Ulsan Natl Inst Sci & Technol, UNIST Cent Res Facil, Ulsan 44919, South Korea 5.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Li, Feng,Yao, Canglang,Jeon, Jong-Pil,et al. Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis[J]. ACS NANO,2023,17(23):24282-24289.
APA	Li, Feng.,Yao, Canglang.,Jeon, Jong-Pil.,Han, Gao-Feng.,Shin, Tae Joo.,...&Baek, Jong-Beom.(2023).Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis.ACS NANO,17(23),24282-24289.
MLA	Li, Feng,et al."Rhodium and Carbon Sites with Strong d-p Orbital Interaction for Efficient Bifunctional Catalysis".ACS NANO 17.23(2023):24282-24289.