| Design of High-Efficiency Hydrogen Evolution Catalysts in a Chiral Crystal | |
| Zhan, Jie1,2; Cao, Yu1,2; Lai, Junwen1,2; Li, Jiangxu2; Ma, Hui1,2; Li, Song3; Liu, Peitao1,2; Chen, Xing-Qiu1,2; Sun, Yan1,2 | |
| 通讯作者 | Chen, Xing-Qiu(xingqiu.chen@imr.ac.cn) ; Sun, Yan(sunyan@imr.ac.cn) |
| 2024-01-08 | |
| 发表期刊 | ACS CATALYSIS
 |
| ISSN | 2155-5435 |
| 卷号 | 14期号:2页码:1030-1036 |
| 摘要 | The design of highly efficient hydrogen evolution reaction (HER) catalysts is one of the most important tasks for electrochemical water splitting in the field of renewable energy resources. In this work, via an effective combination of topologically trivial electronic intensity and the topologically nontrivial energy window, we predicted high catalytic performance in chiral material SiTc, with a close-to-zero hydrogen adsorption Gibbs free energy (-0.062 eV). With both a large intrinsic projected Berry phase and close-to-zero Gibbs free energy, SiTc provides a promising candidate for the HER catalysis reaction. In addition, this work offers an effective strategy for designing more potentially high activity topological electrocatalysts via the combination of topological states and high electronic intensity in metals. |
| 关键词 | hydrogen evolution reaction topologicalenergy window projected Berry phase chiral crystal catalystdesign |
| 资助者 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key R&D Program of China ; Liaoning Province ; China Postdoctoral Science Foundation |
| DOI | 10.1021/acscatal.3c03086 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China[52271016] ; National Natural Science Foundation of China[52188101] ; National Natural Science Foundation of China[2021YFB3501503] ; National Key R&D Program of China[XLYC2203080] ; Liaoning Province[2021M700152] ; Liaoning Province[DFZX202319] ; China Postdoctoral Science Foundation |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| WOS记录号 | WOS:001146507800001 |
| 出版者 | AMER CHEMICAL SOC |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.imr.ac.cn/handle/321006/183596 |
| 专题 | 中国科学院金属研究所 |
| 通讯作者 | Chen, Xing-Qiu; Sun, Yan |
| 作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Northeastern Univ, Sch Mat Sci & Engn, Key Lab Anisotropy & Texture Mat MoE, Shenyang 110819, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhan, Jie,Cao, Yu,Lai, Junwen,et al. Design of High-Efficiency Hydrogen Evolution Catalysts in a Chiral Crystal[J]. ACS CATALYSIS,2024,14(2):1030-1036. |
| APA | Zhan, Jie.,Cao, Yu.,Lai, Junwen.,Li, Jiangxu.,Ma, Hui.,...&Sun, Yan.(2024).Design of High-Efficiency Hydrogen Evolution Catalysts in a Chiral Crystal.ACS CATALYSIS,14(2),1030-1036. |
| MLA | Zhan, Jie,et al."Design of High-Efficiency Hydrogen Evolution Catalysts in a Chiral Crystal".ACS CATALYSIS 14.2(2024):1030-1036. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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