Optimizing spin arrangement by permeability modulation of high-entropy alloys to promote O-O formation for efficient water oxidation

doi:10.1007/s40843-023-2709-5

IMR OpenIR

	Optimizing spin arrangement by permeability modulation of high-entropy alloys to promote O-O formation for efficient water oxidation
	Chen, Zheng-Jie 1,2,3; Zhang, Tao 2,3; Wu, Jiajing 4; Yang, Xinchun 1; Zheng, Yongping 1; Tang, Yongbing 1,5; Yu, Hai-Bin 2,3; Peng, Jing 1,5; Cheng, Hui-Ming 1,5,6
通讯作者	Yu, Hai-Bin(haibinyu@hust.edu.cn) ; Peng, Jing(jing.peng@siat.ac.cn) ; Cheng, Hui-Ming(hm.cheng@siat.ac.cn)
	2024-01-16
发表期刊	SCIENCE CHINA-MATERIALS
ISSN	2095-8226
页码	10
摘要	Magnetic field-triggered spin arrangements have emerged as an intriguing and viable strategy for enhancing the oxygen evolution reaction. However, the magnetic field-enhanced mechanism in high-entropy alloy (HEA) catalysts with strong d-d Coulomb interactions remains incompletely understood. In this study, metal-sheet HEAs with excellent soft-magnetic properties that exhibit remarkable field-enhanced catalysis under a minute magnetic field were designed. The permeability of these HEAs serves as a descriptor for assessing the enhancement. Specifically, the drop in the overpotential of (FeCoNi)(82.5)Cr-17.5 HEAs exceeds 36 mV@10 mA cm(-2) when applying a field of only 50 mT. Furthermore, reduction in overpotential demonstrates a direct linear correlation with the magnetic permeability of the HEAs. Theoretical calculations coupled with in-situ Raman spectroscopy elucidate that applying a magnetic field substantially significantly increases spin density and improves the spin interaction between the 3d electrons of the catalyst and the 2p orbital of the O intermediate. This effectively lowers the energy barrier of the rate-determining step (O ->*OOH), thereby facilitating O-O formation.
关键词	high-entropy alloy magnetic permeability magnetic field spin arrangement oxygen evolution reaction
资助者	National Natural Science Foundation of China ; Shenzhen Basic Research Project ; Science and Technology Foundation of Shenzhen ; Guangdong Basic and Applied Basic Research Foundation ; China Postdoctoral Science Foundation ; Cross Institute Joint Research Youth Team Project of SIAT ; Network and Computing Center of Huazhong University of Science and Technology
DOI	10.1007/s40843-023-2709-5
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52188101] ; National Natural Science Foundation of China[22275205] ; Shenzhen Basic Research Project[JCYJ20200109144616617] ; Science and Technology Foundation of Shenzhen[JCYJ20220530154404010] ; Guangdong Basic and Applied Basic Research Foundation[2023B1515020102] ; Guangdong Basic and Applied Basic Research Foundation[2022A1515110408] ; China Postdoctoral Science Foundation[2022M713270] ; Cross Institute Joint Research Youth Team Project of SIAT[E25427] ; Network and Computing Center of Huazhong University of Science and Technology
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:001150070500003
出版者	SCIENCE PRESS
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/183829
专题	中国科学院金属研究所
通讯作者	Yu, Hai-Bin; Peng, Jing; Cheng, Hui-Ming
作者单位	1.Chinese Acad Sci, Fac Mat Sci & Energy Engn, Shenzhen Inst Adv Technol, Inst Technol Carbon Neutral, Shenzhen 518055, Peoples R China 2.Huazhong Univ Sci & Technol, Wuhan Natl High Magnet Field Ctr, Wuhan 430074, Peoples R China 3.Huazhong Univ Sci & Technol, Sch Phys, Wuhan 430074, Peoples R China 4.Shenzhen Inst Informat Technol, Inst Informat Technol, Shenzhen 518172, Peoples R China 5.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen Key Lab Energy Mat Carbon Neutral, Shenzhen 518055, Peoples R China 6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Chen, Zheng-Jie,Zhang, Tao,Wu, Jiajing,et al. Optimizing spin arrangement by permeability modulation of high-entropy alloys to promote O-O formation for efficient water oxidation[J]. SCIENCE CHINA-MATERIALS,2024:10.
APA	Chen, Zheng-Jie.,Zhang, Tao.,Wu, Jiajing.,Yang, Xinchun.,Zheng, Yongping.,...&Cheng, Hui-Ming.(2024).Optimizing spin arrangement by permeability modulation of high-entropy alloys to promote O-O formation for efficient water oxidation.SCIENCE CHINA-MATERIALS,10.
MLA	Chen, Zheng-Jie,et al."Optimizing spin arrangement by permeability modulation of high-entropy alloys to promote O-O formation for efficient water oxidation".SCIENCE CHINA-MATERIALS (2024):10.