Large magnetocaloric effect in gadolinium-rich silicate NaGd9(SiO4)6O2

doi:10.1016/j.jallcom.2023.173351

IMR OpenIR

	Large magnetocaloric effect in gadolinium-rich silicate NaGd9(SiO4)6O2
	Chen, Zuhua 1,2,3,4,5; Zhang, Chengliang 6; Zhang, Zhengming 6; Yu, Shilin 7,8; Zhang, Guochun 4,5; Tu, Heng 4,5; Wang, Dunhui 1,2,3,6,10; Shen, Jun 9
通讯作者	Wang, Dunhui(wangdh@hdu.edu.cn) ; Shen, Jun(jshen@bit.edu.cn)
	2024-03-05
发表期刊	JOURNAL OF ALLOYS AND COMPOUNDS
ISSN	0925-8388
卷号	976 页码:7
摘要	Magnetic cooling has aroused great interest in cryogenic research due to its high energy efficiency. Due to the large magnetic moment and completely quenched orbital momentum, Gd-based oxides have been promising candidates for cryogenic magnetic refrigerant. In this article, the magnetic properties and magnetocaloric effect of NaGd9(SiO4)6O2 (NGSO) single crystal are investigated. The maximum magnetic entropy change of 60 J & sdot;kg- 1K-1 is observed with the magnetic field changing from 0-7 T at 2.6 K. The large magnetic entropy change can be attributed to high metal/ligand ratio and weak exchange interaction. Particularly, due to the large density of NGSO, the volumetric entropy change is identified to be 382.8 mJ & sdot;cm- 3K-1, which surpasses most reported magnetic refrigerants in volume units. Besides, the excellent refrigerant capacity and adiabatic temperature change have been determined to be as high as 370.4 J & sdot;kg-1 and 7.4 K under the applied field change of 0-7 T and 0-2 T, respectively. These performances suggest that NGSO is a promising candidate for low-temperature
关键词	Magnetic refrigeration Gd-based oxides Single crystal Volumetric entropy change
资助者	National Key Research and Devel- opment Program of China ; National Natural Science Foundation of China ; National Science Fund for Distinguished Young Scholars
DOI	10.1016/j.jallcom.2023.173351
收录类别	SCI
语种	英语
资助项目	National Key Research and Devel- opment Program of China[2022YFB3505101] ; National Natural Science Foundation of China[52271175] ; National Natural Science Foundation of China[52088101] ; National Science Fund for Distinguished Young Scholars[51925605]
WOS研究方向	Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:001151822400001
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/183895
专题	中国科学院金属研究所
通讯作者	Wang, Dunhui; Shen, Jun
作者单位	1.Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China 2.Nanjing Univ, Dept Phys, Nanjing 210093, Peoples R China 3.Nanjing Univ, Jiangsu Prov Key Lab Nanotechnol, Nanjing 210093, Peoples R China 4.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Ctr Crystal Res & Dev,Key Lab Cryogen, Beijing 100190, Peoples R China 5.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 6.Hangzhou Dianzi Univ, Hangzhou 310018, Zhejiang, Peoples R China 7.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 8.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 9.Beijing Inst Technol, Sch Mech Engn, Dept Energy & Power Engn, Beijing 100081, Peoples R China 10.Nanjing Univ, Sch Phys, Nanjing 210093, Peoples R China
推荐引用方式 GB/T 7714	Chen, Zuhua,Zhang, Chengliang,Zhang, Zhengming,et al. Large magnetocaloric effect in gadolinium-rich silicate NaGd9(SiO4)6O2[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2024,976:7.
APA	Chen, Zuhua.,Zhang, Chengliang.,Zhang, Zhengming.,Yu, Shilin.,Zhang, Guochun.,...&Shen, Jun.(2024).Large magnetocaloric effect in gadolinium-rich silicate NaGd9(SiO4)6O2.JOURNAL OF ALLOYS AND COMPOUNDS,976,7.
MLA	Chen, Zuhua,et al."Large magnetocaloric effect in gadolinium-rich silicate NaGd9(SiO4)6O2".JOURNAL OF ALLOYS AND COMPOUNDS 976(2024):7.