Competitive Coordination of Sodium Ions for High-Voltage Sodium Metal Batteries with Fast Reaction Speed

doi:10.1021/jacs.3c11952

IMR OpenIR

	Competitive Coordination of Sodium Ions for High-Voltage Sodium Metal Batteries with Fast Reaction Speed
	Wang, Yaozu 1,2; Yang, Huicong 1,2; Xu, Jipeng 3; Tang, Pei 1,2; Wei, Qian 1,2; Hu, Tianzhao 2; Gao, Xuning 1,2; Guo, Zhenqiang 1,2; Fang, Ruopian 4; Hu, Guangjian 1,2; Bai, Shuo 1,2; Li, Feng 1,2
通讯作者	Yang, Huicong(hcyang@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2024-02-09
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN	0002-7863
页码	9
摘要	The unstable electrode-electrolyte interface and the narrow electrochemical window of normal electrolytes hinder the potential application of high-voltage sodium metal batteries. These problems are actually related to the solvation structure of the electrolyte, which is determined by the competition between cations coordinated with anions or solvent molecules. Herein, we design an electrolyte incorporating ethyl (2,2,2-trifluoroethyl) carbonate and fluoroethylene carbonate, which facilitates a pronounced level of cation-anion coordination within the solvation sheath by enthalpy changes to reduce the overall coordination of cation-solvents and increase sensitivity to salt concentration. Such an electrolyte regulated by competitive coordination leads to highly reversible sodium plating/stripping with extended cycle life and a high Coulombic efficiency of 98.0%, which is the highest reported so far in Na\|\|Cu cells with ester-based electrolytes. Moreover, 4.5 V high-voltage Na\|\|Na3V2(PO4)(2)F-3 cells exhibit a high rate capability up to 20 C and an impressive cycling stability with an 87.1% capacity retention after 250 cycles with limited Na. The proposed strategy of solvation structure modification by regulating the competitive coordination of the cation provides a new direction to achieve stable sodium metal batteries with high energy density and can be further extended to other battery systems by controlling enthalpy changes of the solvation structure.
资助者	Chinese Academy of Sciences ; National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; China Postdoctoral Science Foundation
DOI	10.1021/jacs.3c11952
收录类别	SCI
语种	英语
资助项目	Chinese Academy of Sciences[2022YFB3803400] ; Chinese Academy of Sciences[2021YFB2800200] ; National Key R&D Program of China[22209189] ; National Key R&D Program of China[52020105010] ; National Key R&D Program of China[51927803] ; National Key R&D Program of China[52188101] ; National Key R&D Program of China[52072378] ; National Natural Science Foundation of China[XDA22010602] ; Strategic Priority Research Program of Chinese Academy of Sciences[2022M723216] ; China Postdoctoral Science Foundation
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001166446300001
出版者	AMER CHEMICAL SOC
引用统计	被引频次：33[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/184465
专题	中国科学院金属研究所
通讯作者	Yang, Huicong; Li, Feng
作者单位	1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.East China Univ Sci & Technol, Sch Chem & Mol Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China 4.Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia
推荐引用方式 GB/T 7714	Wang, Yaozu,Yang, Huicong,Xu, Jipeng,et al. Competitive Coordination of Sodium Ions for High-Voltage Sodium Metal Batteries with Fast Reaction Speed[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2024:9.
APA	Wang, Yaozu.,Yang, Huicong.,Xu, Jipeng.,Tang, Pei.,Wei, Qian.,...&Li, Feng.(2024).Competitive Coordination of Sodium Ions for High-Voltage Sodium Metal Batteries with Fast Reaction Speed.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,9.
MLA	Wang, Yaozu,et al."Competitive Coordination of Sodium Ions for High-Voltage Sodium Metal Batteries with Fast Reaction Speed".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2024):9.