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Coarsening mechanism of over-aged 6-Ni2Si nanoscale precipitates in Cu-Ni-Si-Cr-Mg alloy
Li, Ying-Huan1,2; Chen, Shuai-Feng2; Wang, Song-Wei2; Song, Hong-Wu2; Zhang, Shi-Hong2
通讯作者Song, Hong-Wu(hwsong@imr.ac.cn)
2024-03-01
发表期刊MATERIALS CHARACTERIZATION
ISSN1044-5803
卷号209页码:12
摘要6-Ni2Si precipitate is the crucial strengthening phase in Cu-Ni-Si alloy, and its coarsening behavior and mechanism impose dramatic effects on mechanical properties. In this paper, Cu-3Ni-0.7Si-0.1Cr-0.05 Mg (wt%) alloy was prepared to systematically investigate the coarsening behavior and elucidate the coarsening mechanism of 6-Ni2Si precipitate during over -aging treatment. Featured core -shell structure was observed via careful characterization during coarsening of 6-Ni2Si phase. Specifically, the core structure was stable 6-Ni2Si, while the shell structure was a metastable interface composed of Cu, Ni and Si elements. At later over -aging stage, the core -shell structure completely transformed into a stable and coarsened 6-Ni2Si phase being coherent with the Cu matrix. It is confirmed for the first time that the coarsening process of 6-Ni2Si precipitate can be interpreted by the transinterface -diffusion -controlled (TIDC) coarsening theory. The core -shell structure was caused by the disparity between the diffusion activation energy and diffusion rate of Ni, Si, and Cu from the perspective of diffusion kinetics. Moreover, the presence of trace amounts of Cr and Mg components exhibited little effect on the coarsening process of 6-Ni2Si. During over -aging, tensile strength dramatically decreased owing to diminishing precipitation strengthening effect from coarsening of 6-Ni2Si precipitates.
关键词Cu-Ni-Si-Cr-Mg alloy 6-Ni2Si coarsening Core-shell structure TIDC theory Diffusion kinetics
资助者Key Research and Development Program of Jiangxi Province ; CAS ; Institute of Metal Research, Chinese Academy of Sciences
DOI10.1016/j.matchar.2024.113693
收录类别SCI
语种英语
资助项目Key Research and Development Program of Jiangxi Province[20203ABC28W004] ; CAS[172GJHZ2022054GC] ; Institute of Metal Research, Chinese Academy of Sciences[E055A501]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Materials Science, Characterization & Testing
WOS记录号WOS:001179368300001
出版者ELSEVIER SCIENCE INC
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/184662
专题中国科学院金属研究所
通讯作者Song, Hong-Wu
作者单位1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
2.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Li, Ying-Huan,Chen, Shuai-Feng,Wang, Song-Wei,et al. Coarsening mechanism of over-aged 6-Ni2Si nanoscale precipitates in Cu-Ni-Si-Cr-Mg alloy[J]. MATERIALS CHARACTERIZATION,2024,209:12.
APA Li, Ying-Huan,Chen, Shuai-Feng,Wang, Song-Wei,Song, Hong-Wu,&Zhang, Shi-Hong.(2024).Coarsening mechanism of over-aged 6-Ni2Si nanoscale precipitates in Cu-Ni-Si-Cr-Mg alloy.MATERIALS CHARACTERIZATION,209,12.
MLA Li, Ying-Huan,et al."Coarsening mechanism of over-aged 6-Ni2Si nanoscale precipitates in Cu-Ni-Si-Cr-Mg alloy".MATERIALS CHARACTERIZATION 209(2024):12.
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