| Scalable Synthesis of High-Quality Ultrathin Ferroelectric Magnesium Molybdenum Oxide | |
| Zhang, Xingxing1; Cheng, Mo1; Dai, Jiuxiang1; Yang, Qianqian2; Zhang, Ye3,4; Dong, Baojuan5; Tao, Xinwei1; Zou, Jingyi6; Jin, Zhitong1; Liu, Feng7; Wu, Zhenghan7; Hu, Xianyu1; Zheng, Zemin1; Shi, Zhiwen7; Jiang, Shengwei7; Zhang, Linxing2; Yang, Teng3,4; Zhang, Xu6; Zhou, Lin1 | |
| 通讯作者 | Zhou, Lin(linzhou@sjtu.edu.cn) |
| 2024-03-19 | |
| 发表期刊 | ADVANCED MATERIALS
 |
| ISSN | 0935-9648 |
| 页码 | 8 |
| 摘要 | The development of ultrathin, stable ferroelectric materials is crucial for advancing high-density, low-power electronic devices. Nonetheless, ultrathin ferroelectric materials are rare due to the critical size effect. Here, a novel ferroelectric material, magnesium molybdenum oxide (Mg2Mo3O8) is presented. High-quality ultrathin Mg2Mo3O8 crystals are synthesized using chemical vapor deposition (CVD). Ultrathin Mg2Mo3O8 has a wide bandgap (approximate to 4.4 eV) and nonlinear optical response. Mg2Mo3O8 crystals of varying thicknesses exhibit out-of-plane ferroelectric properties at room temperature, with ferroelectricity retained even at a 2 nm thickness. The Mg2Mo3O8 exhibits a relatively large remanent polarization ranging from 33 to 52 mu C cm(-)(2), which is tunable by changing its thickness. Notably, Mg2Mo3O8 possesses a high Curie temperature (>980 degrees C) across various thicknesses. Moreover, the as-grown Mg2Mo3O8 crystals display remarkable stability under harsh environments. This work introduces nolanites-type crystal into ultrathin ferroelectrics. The scalable synthesis of stable ultrathin ferroelectric Mg2Mo3O8 expands the scope of ferroelectric materials and may prosper applications of ferroelectrics. |
| 关键词 | chemical vapor deposition Mg2Mo3O8 nolanites ultrathin ferroelectric materials |
| 资助者 | National Natural Science Foundation of China ; National Key R&D Program of China ; Yangyang Development Fund |
| DOI | 10.1002/adma.202308550 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China ; National Key R&D Program of China[2021YFA1401400] ; National Key R&D Program of China[2021YFA1400100] ; Yangyang Development Fund ; [12174250] ; [12141404] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| WOS记录号 | WOS:001187203900001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.imr.ac.cn/handle/321006/184767 |
| 专题 | 中国科学院金属研究所 |
| 通讯作者 | Zhou, Lin |
| 作者单位 | 1.Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China 2.Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Beijing Adv Innovat Ctr Mat Genome Engn, Beijing 100083, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Beijing, Peoples R China 4.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 5.Shanxi Univ, Inst Optoelect, Collaborat Innovat Ctr Extreme Opt, State Key Lab Quantum Opt & Quantum Opt Devices, Taiyuan 030006, Peoples R China 6.Carnegie Mellon Univ, Dept Elect & Comp Engn, Pittsburgh, PA 15213 USA 7.Shanghai Jiao Tong Univ, Sch Phys & Astron, Shanghai 200240, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xingxing,Cheng, Mo,Dai, Jiuxiang,et al. Scalable Synthesis of High-Quality Ultrathin Ferroelectric Magnesium Molybdenum Oxide[J]. ADVANCED MATERIALS,2024:8. |
| APA | Zhang, Xingxing.,Cheng, Mo.,Dai, Jiuxiang.,Yang, Qianqian.,Zhang, Ye.,...&Zhou, Lin.(2024).Scalable Synthesis of High-Quality Ultrathin Ferroelectric Magnesium Molybdenum Oxide.ADVANCED MATERIALS,8. |
| MLA | Zhang, Xingxing,et al."Scalable Synthesis of High-Quality Ultrathin Ferroelectric Magnesium Molybdenum Oxide".ADVANCED MATERIALS (2024):8. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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