Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling | |
Wei, Yufeng1; Pan, Jie1,2; Sun, Yonghao3,4; Li, Ning1; Zhang, Cheng1; Wang, Weihua3,4; Liu, Lin1 | |
通讯作者 | Pan, Jie(jpan@hust.edu.cn) ; Sun, Yonghao(ysun58@iphy.ac.cn) ; Liu, Lin(lliu2000@mail.hust.edu.cn) |
2024-02-22 | |
发表期刊 | SCIENCE CHINA-MATERIALS
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ISSN | 2095-8226 |
页码 | 9 |
摘要 | Cryogenic thermal-cycling (CTC) is a promising method for the rejuvenation of metallic glasses (MGs). Although seemingly arbitrary, the direction of energy change in MGs following CTC sometimes results in relaxation rather than rejuvenation. By demonstrating enthalpy relaxation in a shear band (SB) and enthalpy rejuvenation in the metallic-glass matrix, the current work demonstrates that the initial state of the specimen matters. Micro-hardness, nano-indentation loading curves, and the shapes of indents all support the bidirectional trends. Notably, after subjecting the specimen to 100 cryogenic thermal-cycles, the enthalpy and hardness tend to converge into an equilibrium value. It is discovered that CTC can accelerate the structural relaxation of SB at room temperature, a phenomenon that thermal annealing at the upper temperature (353 K) of CTC cannot achieve. Additionally, the experimental results have been elucidated by adapting the free-volume model. The work provides new insights into the functionalities of CTC and illuminates the initial state of the metallic-glass sample upon reversing the direction of enthalpy change. |
关键词 | metallic glasses cryogenic thermal-cycling rejuvenation relaxation energy state |
资助者 | National Natural Science Foundation of China ; Key R&D Program of Hubei ; Basic Research Support Program of Huazhong University of Science and Technology ; Young Elite Scientists Sponsorship Program by China Association for Science and Technology |
DOI | 10.1007/s40843-023-2759-9 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[52022100] ; National Natural Science Foundation of China[52192604] ; National Natural Science Foundation of China[51971097] ; National Natural Science Foundation of China[51971239] ; National Natural Science Foundation of China[92263103] ; Key R&D Program of Hubei[2022BAA023] ; Basic Research Support Program of Huazhong University of Science and Technology[5003110121] ; Young Elite Scientists Sponsorship Program by China Association for Science and Technology |
WOS研究方向 | Materials Science |
WOS类目 | Materials Science, Multidisciplinary |
WOS记录号 | WOS:001172655900002 |
出版者 | SCIENCE PRESS |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/184796 |
专题 | 中国科学院金属研究所 |
通讯作者 | Pan, Jie; Sun, Yonghao; Liu, Lin |
作者单位 | 1.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mold Technol, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China 4.Songshan Lake Mat Lab, Dongguan 523808, Peoples R China |
推荐引用方式 GB/T 7714 | Wei, Yufeng,Pan, Jie,Sun, Yonghao,et al. Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling[J]. SCIENCE CHINA-MATERIALS,2024:9. |
APA | Wei, Yufeng.,Pan, Jie.,Sun, Yonghao.,Li, Ning.,Zhang, Cheng.,...&Liu, Lin.(2024).Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling.SCIENCE CHINA-MATERIALS,9. |
MLA | Wei, Yufeng,et al."Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling".SCIENCE CHINA-MATERIALS (2024):9. |
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