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Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling
Wei, Yufeng1; Pan, Jie1,2; Sun, Yonghao3,4; Li, Ning1; Zhang, Cheng1; Wang, Weihua3,4; Liu, Lin1
通讯作者Pan, Jie(jpan@hust.edu.cn) ; Sun, Yonghao(ysun58@iphy.ac.cn) ; Liu, Lin(lliu2000@mail.hust.edu.cn)
2024-02-22
发表期刊SCIENCE CHINA-MATERIALS
ISSN2095-8226
页码9
摘要Cryogenic thermal-cycling (CTC) is a promising method for the rejuvenation of metallic glasses (MGs). Although seemingly arbitrary, the direction of energy change in MGs following CTC sometimes results in relaxation rather than rejuvenation. By demonstrating enthalpy relaxation in a shear band (SB) and enthalpy rejuvenation in the metallic-glass matrix, the current work demonstrates that the initial state of the specimen matters. Micro-hardness, nano-indentation loading curves, and the shapes of indents all support the bidirectional trends. Notably, after subjecting the specimen to 100 cryogenic thermal-cycles, the enthalpy and hardness tend to converge into an equilibrium value. It is discovered that CTC can accelerate the structural relaxation of SB at room temperature, a phenomenon that thermal annealing at the upper temperature (353 K) of CTC cannot achieve. Additionally, the experimental results have been elucidated by adapting the free-volume model. The work provides new insights into the functionalities of CTC and illuminates the initial state of the metallic-glass sample upon reversing the direction of enthalpy change.
关键词metallic glasses cryogenic thermal-cycling rejuvenation relaxation energy state
资助者National Natural Science Foundation of China ; Key R&D Program of Hubei ; Basic Research Support Program of Huazhong University of Science and Technology ; Young Elite Scientists Sponsorship Program by China Association for Science and Technology
DOI10.1007/s40843-023-2759-9
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[52022100] ; National Natural Science Foundation of China[52192604] ; National Natural Science Foundation of China[51971097] ; National Natural Science Foundation of China[51971239] ; National Natural Science Foundation of China[92263103] ; Key R&D Program of Hubei[2022BAA023] ; Basic Research Support Program of Huazhong University of Science and Technology[5003110121] ; Young Elite Scientists Sponsorship Program by China Association for Science and Technology
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
WOS记录号WOS:001172655900002
出版者SCIENCE PRESS
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/184796
专题中国科学院金属研究所
通讯作者Pan, Jie; Sun, Yonghao; Liu, Lin
作者单位1.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mold Technol, Wuhan 430074, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China
4.Songshan Lake Mat Lab, Dongguan 523808, Peoples R China
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GB/T 7714
Wei, Yufeng,Pan, Jie,Sun, Yonghao,et al. Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling[J]. SCIENCE CHINA-MATERIALS,2024:9.
APA Wei, Yufeng.,Pan, Jie.,Sun, Yonghao.,Li, Ning.,Zhang, Cheng.,...&Liu, Lin.(2024).Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling.SCIENCE CHINA-MATERIALS,9.
MLA Wei, Yufeng,et al."Accelerating structural relaxation of shear band at ambient conditions through cryogenic thermal-cycling".SCIENCE CHINA-MATERIALS (2024):9.
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