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Nitrogen-Substituting Carbon Significantly Improves Softening Resistance of H13 Hot-Work Die Steel
Wang, Hai-Jian1; Feng, Hao1,2; Li, Hua-Bing1,2; Zhou, Gang3; Zhu, Hong-Chun1,4; Zhang, Shu-Cai1; Jiang, Zhou-Hua1,2
通讯作者Feng, Hao(fenghao@smm.neu.edu.cn) ; Zhou, Gang(gzhou@imr.ac.cn)
2024-03-21
发表期刊METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE
ISSN1073-5623
页码16
摘要In this study, the thermal stability of H13 hot-work tool steel was significantly improved through the use of nitrogen as a substitute for carbon. The results indicated that the 0.3C-0.2N and 0.2C-0.3N steels exhibited better hardness stability than H13 steel (0.4C-0N). In particular, the 0.2C-0.3N steel exhibited substantially improved hardness stability. The softening resistance mechanism was revealed from the perspectives of precipitates, dislocations, laths, and variants through first-principles calculations, thermodynamic and kinetic models, and variant reconstruction. First, for precipitate stability, the results of first-principles calculations and kinetic analysis showed that substituting N with C reduced the formation energy of carbides and facilitated the formation of carbonitrides. For 0.2C-0.3N steel, which had the highest activation energy, both the diffusion of alloying elements and the coarsening of carbonitrides were significantly inhibited. Second, in terms of dislocation evolution, the most stable lattice constant, highest interstitial atom content and lowest carbide precipitation content were the keys to inhibiting dislocation recovery. Finally, the dislocation and heat-induced boundary migration stimulated the selection of variants, resulting in the coarsening and coalescence of laths. The change from V17 to V1 variant pairs was dominant for the lath coalescence of 0.2C-0.3N steel.
资助者National Natural Science Foundation of China ; Science Fund for Distinguished Young Scholars of Liaoning Province ; Program of Introducing Talents of Discipline to Universities
DOI10.1007/s11661-024-07367-y
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[52374331] ; National Natural Science Foundation of China[52325406] ; National Natural Science Foundation of China[U1960203] ; Science Fund for Distinguished Young Scholars of Liaoning Province[2023JH6/100500008] ; Program of Introducing Talents of Discipline to Universities[B21001]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:001190083700001
出版者SPRINGER
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/185351
专题中国科学院金属研究所
通讯作者Feng, Hao; Zhou, Gang
作者单位1.Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
2.Northeastern Univ, Key Lab Ecol Met Multimet Ores, Minist Educ, Shenyang 110819, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shi Changxu Innovat Ctr Adv Mat, Shenyang 110016, Peoples R China
4.Northeastern Univ, Inst Frontier Technol Low Carbon Steelmaking, Shenyang 110819, Peoples R China
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GB/T 7714
Wang, Hai-Jian,Feng, Hao,Li, Hua-Bing,et al. Nitrogen-Substituting Carbon Significantly Improves Softening Resistance of H13 Hot-Work Die Steel[J]. METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE,2024:16.
APA Wang, Hai-Jian.,Feng, Hao.,Li, Hua-Bing.,Zhou, Gang.,Zhu, Hong-Chun.,...&Jiang, Zhou-Hua.(2024).Nitrogen-Substituting Carbon Significantly Improves Softening Resistance of H13 Hot-Work Die Steel.METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE,16.
MLA Wang, Hai-Jian,et al."Nitrogen-Substituting Carbon Significantly Improves Softening Resistance of H13 Hot-Work Die Steel".METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE (2024):16.
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