Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction

doi:10.1016/j.apsusc.2024.159904

IMR OpenIR

	Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction
	Liu, Jie 1,2; Zhong, Xia 2,3; Gao, Li 2,3; Zhang, Ying 2,4; Wang, Ziru 1,2; Zhang, Xia 1; Zhang, Bingsen 2,3
通讯作者	Zhang, Xia(xzhang@mail.neu.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn)
	2024-06-30
发表期刊	APPLIED SURFACE SCIENCE
ISSN	0169-4332
卷号	659 页码:8
摘要	The Suzuki-Miyaura reaction is one of the most effective routes for the construction of carbon-carbon bonds, due to the obvious advantages of mild reaction conditions, wide range of functional group tolerance, simplicity of operation, and environmental friendliness. However, these reactions highly depend on the development of the active and stable catalysts. Herein, the hollow hexagonal prismatic silicalite-1 (HS-1) zeolite-supported palladium nanoparticles (Pd NPs) were synthesized and applied as a catalyst in Suzuki-Miyaura reaction. The experimental results show that 2.0Pd/HS-1 is an efficient and stable catalyst, which can achieve a high conversion rate (>99.9 %) in a short time (45 min) and can be recycled. Further studies show that 2.0Pd/HS-1 has abundant mesopores, which are favorable for exposing more active sites and promoting the transfer of reactants around the catalysts, thus improving the contact opportunities between the catalysts and the feedstock. Moreover, its proper acid sites as well as metal-zeolite interactions can modulate the electronic state of Pd, and thus improve the conversion of bromobenzene. This work provides new insights into the design, synthesis and applications of highly efficient hollow silicalite-1 zeolite loaded metal catalysts.
关键词	Suzuki-Miyaura reaction Palladium Zeolite Acid sites
资助者	National Natural Science Foundation of China ; Research Fund of Shenyang National Laboratory for Materials Science
DOI	10.1016/j.apsusc.2024.159904
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52161145403] ; National Natural Science Foundation of China[22072164] ; Research Fund of Shenyang National Laboratory for Materials Science
WOS研究方向	Chemistry ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:001215195600001
出版者	ELSEVIER
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/185739
专题	中国科学院金属研究所
通讯作者	Zhang, Xia; Zhang, Bingsen
作者单位	1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 4.Liaoning Petrochem Univ, Sch Petrochem Engn, Fushun 113001, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Liu, Jie,Zhong, Xia,Gao, Li,et al. Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction[J]. APPLIED SURFACE SCIENCE,2024,659:8.
APA	Liu, Jie.,Zhong, Xia.,Gao, Li.,Zhang, Ying.,Wang, Ziru.,...&Zhang, Bingsen.(2024).Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction.APPLIED SURFACE SCIENCE,659,8.
MLA	Liu, Jie,et al."Hierarchical porous Pd/HS-1 zeolite as an efficient and reusable catalysts for Suzuki-Miyaura reaction".APPLIED SURFACE SCIENCE 659(2024):8.