Novel Alkane Dehydrogenation Routes via Tailored Catalysts

doi:10.1002/cctc.202400410

IMR OpenIR

	Novel Alkane Dehydrogenation Routes via Tailored Catalysts
	Dai, Xueya 1,2; Qi, Wei 1,2
通讯作者	Qi, Wei(wqi@imr.ac.cn)
	2024-05-02
发表期刊	CHEMCATCHEM
ISSN	1867-3880
页码	7
摘要	Alkane dehydrogenation to alkene represents a promising alternative route for conventional petroleum cracking processes heavily reliant on fossil resources. This Concept outlines the latest advancements of novel alkane dehydrogenation routes that offer potential solutions to intrinsic problems existing in routine direct dehydrogenation or oxidative dehydrogenation reactions, including CO2 assisted alkane dehydrogenation, chemical looping alkane oxidative dehydrogenation, dual-path dehydrogenation and auto-accelerated multiple alkane dehydrogenation route. These novel reaction routes exhibit unique advantages in enhancing the activity, selectivity and stability of the alkane dehydrogenation reaction system. The rational design of novel catalysts and proper choice of the reaction condition that well-fitted these reaction routes is the key for achieving highly efficient and stable alkane dehydrogenation process. These present examples in this manuscript also highlight the importance of fundamental in-depth understandings on the mechanism and structure-function relations, which is the foundation for developing novel alkane dehydrogenation routes for practical applications. Novel alkane dehydrogenation routes, including CO2 assisted dehydrogenation, chemical looping oxidative dehydrogenation, dual-path dehydrogenation and auto-accelerated multiple alkane dehydrogenation routes, are highlighted in this Concept. Rational design of corresponding catalysts, proper choice of reaction conditions and the in depth understandings on the reaction mechanism and structure-function relations are summarized as the key in these reaction routes. image
关键词	alkane dehydrogenation reaction routes non-mental catalysts reaction mechanisms structure-function relations
资助者	NSFC of China ; Natural Science Foundation of Liaoning Province of China ; Baowu Low Carbon Metallurgy Innovation Foudation
DOI	10.1002/cctc.202400410
收录类别	SCI
语种	英语
资助项目	NSFC of China ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; Baowu Low Carbon Metallurgy Innovation Foudation[BWLCF202113] ; [22072163]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:001214528800001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/185834
专题	中国科学院金属研究所
通讯作者	Qi, Wei
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Dai, Xueya,Qi, Wei. Novel Alkane Dehydrogenation Routes via Tailored Catalysts[J]. CHEMCATCHEM,2024:7.
APA	Dai, Xueya,&Qi, Wei.(2024).Novel Alkane Dehydrogenation Routes via Tailored Catalysts.CHEMCATCHEM,7.
MLA	Dai, Xueya,et al."Novel Alkane Dehydrogenation Routes via Tailored Catalysts".CHEMCATCHEM (2024):7.