Organosulfur Cathodes in Lithium Metal Batteries: Bridging the Gap between Fundamentals and Practical Applications

doi:10.1002/adfm.202405122

IMR OpenIR

	Organosulfur Cathodes in Lithium Metal Batteries: Bridging the Gap between Fundamentals and Practical Applications
	Zhang, Xiaoyin 1,2,3; Yu, Tong 1; Yang, Shuaiyi 1,2; Qu, Zhuoyan 1,2; Xiao, Ru 1,2; Wang, Guoxiu 4; Sun, Zhenhua 1,2; Li, Feng 1,2
通讯作者	Wang, Guoxiu(Guoxiu.Wang@uts.edu.au) ; Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2024-05-11
发表期刊	ADVANCED FUNCTIONAL MATERIALS
ISSN	1616-301X
页码	28
摘要	High-specific energy sulfur-based cathodes have attracted considerable interest in lithium batteries. Organosulfur cathodes offer inherent advantages of high element abundance and an extended cycling life, aligning with the evolving requirements of future energy storage devices. Over the past decade, research efforts have been devoted to optimizing electrochemical performance through the rich and tunable molecular structures of organosulfur compounds. To further advance the fundamental research and practical application of lithium-organosulfur batteries, a systematical analysis of the correlation between the molecular structures and electrochemical mechanisms of organosulfur cathodes is imperative. This involves deriving the key parameters at the cell level and investigating the feasibility. In this review, the thermodynamics, reaction processes, and electrochemical kinetics of organosulfur cathodes, grounded in fundamental theories of electrochemistry and materials science are discussed. Expanding the insights, comparisons among elemental sulfur, organosulfur, and n-type organic cathodes (e.g., carbonyl cathodes) are drawn. The gap between fundamentals and practical applications targeting 500 Wh kg-1 lithium organosulfur batteries is highlighted through energy density calculations and identification of key factors affecting pouch cells. Finally, potential strategies and prospects for the overall design of advanced lithium-organosulfur batteries are proposed, considering both theoretical foundations and practical implementations. From the viewpoint of thermodynamics, conversion process, and reaction kinetics, this review provides a new insight to understand the electrochemical mechanisms of organosulfur cathodes in lithium batteries, aiming to bridge the gap between fundamentals and practical applications. A roadmap toward 500 Wh kg-1 lithium-organosulfur proposed points out a promising prospect for their application. image
关键词	electrochemical mechanisms lithium metal batteries lithium-sulfur batteries organosulfur cathodes practical prospects
资助者	National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Science ; National Key Research and Development Program of China ; DNL Cooperation Fund, CAS
DOI	10.1002/adfm.202405122
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Science[XDA22010602] ; National Key Research and Development Program of China[2021YFB2800201] ; National Key Research and Development Program of China[2021YFB3800301] ; DNL Cooperation Fund, CAS[DNL202019] ; [22379151] ; [51972313] ; [52020105010] ; [51927803] ; [52188101]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:001218012700001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/185959
专题	中国科学院金属研究所
通讯作者	Wang, Guoxiu; Sun, Zhenhua; Li, Feng
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Nankai Univ, Renewable Energy Convers & Storage Ctr RECAST, Key Lab Adv Energy Mat Chem, Minist Educ,Coll Chem, Tianjin 300071, Peoples R China 4.Univ Technol Sydney, Fac Sci, Ctr Clean Energy Technol, Sch Math & Phys Sci, Sydney, NSW 2007, Australia
推荐引用方式 GB/T 7714	Zhang, Xiaoyin,Yu, Tong,Yang, Shuaiyi,et al. Organosulfur Cathodes in Lithium Metal Batteries: Bridging the Gap between Fundamentals and Practical Applications[J]. ADVANCED FUNCTIONAL MATERIALS,2024:28.
APA	Zhang, Xiaoyin.,Yu, Tong.,Yang, Shuaiyi.,Qu, Zhuoyan.,Xiao, Ru.,...&Li, Feng.(2024).Organosulfur Cathodes in Lithium Metal Batteries: Bridging the Gap between Fundamentals and Practical Applications.ADVANCED FUNCTIONAL MATERIALS,28.
MLA	Zhang, Xiaoyin,et al."Organosulfur Cathodes in Lithium Metal Batteries: Bridging the Gap between Fundamentals and Practical Applications".ADVANCED FUNCTIONAL MATERIALS (2024):28.