Ethanol steam reforming over Ni/ZSM-5 nanosheet for hydrogen production

doi:10.1016/j.cjche.2023.12.006

IMR OpenIR

	Ethanol steam reforming over Ni/ZSM-5 nanosheet for hydrogen production
	Suriya, Porapak 1,2; Xu, Shanshan 1; Ding, Shengzhe 1; Chansai, Sarayute 1; Jiao, Yilai 3,4; Hurd, Joseph 1; Lee, Daniel 1; Zhang, Yuxin 1; Hardacre, Christopher 1; Reubroycharoen, Prasert 5,6; Fan, Xiaolei 1,7
通讯作者	Xu, Shanshan(shanshan.xu@manchester.ac.uk) ; Reubroycharoen, Prasert(prasert.r@chula.ac.th) ; Fan, Xiaolei(xiaolei.fan@manchester.ac.uk)
	2024-03-01
发表期刊	CHINESE JOURNAL OF CHEMICAL ENGINEERING
ISSN	1004-9541
卷号	67 页码:247-256
摘要	Compared to reforming reactions using hydrocarbons, ethanol steam reforming (ESR) is a sustainable alternative for hydrogen (H2) production since ethanol can be produced sustainably using biomass. This work explores the catalyst design strategies for preparing the Ni supported on ZSM-5 zeolite catalysts to promote ESR. Specifically, two-dimensional ZSM-5 nanosheet and conventional ZSM-5 crystal were used as the catalyst carriers and two synthesis strategies, i.e., in situ encapsulation and wet impregnation method, were employed to prepare the catalysts. Based on the comparative characterization of the catalysts and comparative catalytic assessments, it was found that the combination of the in situ encapsulation synthesis and the ZSM-5 nanosheet carrier was the effective strategy to develop catalysts for promoting H2 production via ESR due to the improved mass transfer (through the 2-D structure of ZSM-5 nanosheet) and formation of confined small Ni nanoparticles (resulted via the in situ encapsulation synthesis). In addition, the resulting ZSM-5 nanosheet supported Ni catalyst also showed high Ni dispersion and high accessibility to Ni sites by the reactants, being able to improve the activity and stability of catalysts and suppress metal sintering and coking during ESR at high reaction temperatures. Thus, the Ni supported on ZSM-5 nanosheet catalyst prepared by encapsulation showed the stable performance with -88% ethanol conversion and -65% H2 yield achieved during a 48-h longevity test at 550 degrees C. (c) 2024 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd., All rights reserved. This is an open access article under the CC BY license (http://creativecommons.org/lice nses/by/4.0/).
关键词	ZSM-5 nanosheet In situ encapsulation Ni catalyst Ethanol steam reforming Hydrogen production
资助者	European Union ; Science Achievement Scholarship of Thailand (SAST) for her research secondment at The University of Manchester ; National Natural Science Foundation of China
DOI	10.1016/j.cjche.2023.12.006
收录类别	SCI
语种	英语
资助项目	European Union[872102] ; Science Achievement Scholarship of Thailand (SAST) for her research secondment at The University of Manchester ; National Natural Science Foundation of China[22378407]
WOS研究方向	Engineering
WOS类目	Engineering, Chemical
WOS记录号	WOS:001217784300001
出版者	CHEMICAL INDUSTRY PRESS CO LTD
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/186063
专题	中国科学院金属研究所
通讯作者	Xu, Shanshan; Reubroycharoen, Prasert; Fan, Xiaolei
作者单位	1.Univ Manchester, Sch Engn, Dept Chem Engn, Manchester M13 9PL, England 2.Chulalongkorn Univ, Fac Sci, Program Petrochemistry & Polymer Sci, Bangkok 10330, Thailand 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Liaoning Acad Mat, Shenyang 110167, Peoples R China 5.Chulalongkorn Univ, Fac Sci, Ctr Excellence Catalysis Bioenergy & Renewable Che, Bangkok 10330, Thailand 6.Chulalongkorn Univ, Fac Sci, Dept Chem Technol, Bangkok 10330, Thailand 7.Univ Nottingham Ningbo China, Nottingham Ningbo China Beacons Excellence Res & I, Ningbo 315100, Peoples R China
推荐引用方式 GB/T 7714	Suriya, Porapak,Xu, Shanshan,Ding, Shengzhe,et al. Ethanol steam reforming over Ni/ZSM-5 nanosheet for hydrogen production[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2024,67:247-256.
APA	Suriya, Porapak.,Xu, Shanshan.,Ding, Shengzhe.,Chansai, Sarayute.,Jiao, Yilai.,...&Fan, Xiaolei.(2024).Ethanol steam reforming over Ni/ZSM-5 nanosheet for hydrogen production.CHINESE JOURNAL OF CHEMICAL ENGINEERING,67,247-256.
MLA	Suriya, Porapak,et al."Ethanol steam reforming over Ni/ZSM-5 nanosheet for hydrogen production".CHINESE JOURNAL OF CHEMICAL ENGINEERING 67(2024):247-256.