Atmosphere-Dependent Strong Metal-Support Interactions in Au/ZnO Catalysts and Their Overlayer Permeability

doi:10.1021/acscatal.4c02124

IMR OpenIR

	Atmosphere-Dependent Strong Metal-Support Interactions in Au/ZnO Catalysts and Their Overlayer Permeability
	Wu, Guandong 1,2; Jiang, Yiwei 1; Niu, Yiming 3; Zhang, Bingsen 3; Li, Lin 4; Xu, Li 5; He, Yufei 1,6; Wang, Junhu 2; Li, Dianqing 1
通讯作者	He, Yufei(yfhe@mail.buct.edu.cn) ; Wang, Junhu(wangjh@dicp.ac.cn)
	2024-05-21
发表期刊	ACS CATALYSIS
ISSN	2155-5435
页码	9
摘要	The oxidative strong metal-support interaction (O-SMSI) emerges as a pioneering approach for promoting the formation of overlayers, which has garnered significant interest in the exploration of the synthesis of O-SMSI materials. However, the manipulation of the overlayer is rarely discussed and presents a challenge due to its trace presence on the nanoparticle (NP) surface, which impedes the development and utilization of the O-SMSI. In this work, we demonstrate a strong correlation between the treatment atmosphere and the state of the permeable overlayer in the Au/ZnO catalyst. The ZnO overlayer can be formed in both oxidative and inert atmospheres, but the permeability of the overlayer occurs under an oxidative atmosphere. The difference in the permeabilities of the overlayer, at similar particle sizes, leads to a reaction rate difference of approximately 1.4 times. While the permeability of the ZnO overlayer is improved by an oxidative atmosphere treatment, it is also accompanied by an increase in the geometric strain in the ZnO matrix. The permeable ZnO formation is related to the process of gold species insertion into the ZnO matrix, as indicated by density functional theory calculations. This study is the first to describe the role of O-2 in manipulating the O-SMSI and suboxide overlayers, offering a potential method for surface engineering.
关键词	gold heterogeneous catalysis ZnO overlayer permeability strong metal-support interaction
资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences ; China Postdoctoral Science Foundation
DOI	10.1021/acscatal.4c02124
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[2022YFA1506200] ; National Key R&D Program of China[21961142006] ; National Key R&D Program of China[U22A20394] ; National Natural Science Foundation of China[121421KYSB20170020] ; International Partnership Program of Chinese Academy of Sciences[2022M723086] ; China Postdoctoral Science Foundation
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:001228925700001
出版者	AMER CHEMICAL SOC
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/186370
专题	中国科学院金属研究所
通讯作者	He, Yufei; Wang, Junhu
作者单位	1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Adv Mossbauer Spect, Mossbauer Effect Data Center, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 5.Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Henan, Peoples R China 6.Quzhou Inst Innovat Resource Chem Engn, Quzhou 324000, Peoples R China
推荐引用方式 GB/T 7714	Wu, Guandong,Jiang, Yiwei,Niu, Yiming,et al. Atmosphere-Dependent Strong Metal-Support Interactions in Au/ZnO Catalysts and Their Overlayer Permeability[J]. ACS CATALYSIS,2024:9.
APA	Wu, Guandong.,Jiang, Yiwei.,Niu, Yiming.,Zhang, Bingsen.,Li, Lin.,...&Li, Dianqing.(2024).Atmosphere-Dependent Strong Metal-Support Interactions in Au/ZnO Catalysts and Their Overlayer Permeability.ACS CATALYSIS,9.
MLA	Wu, Guandong,et al."Atmosphere-Dependent Strong Metal-Support Interactions in Au/ZnO Catalysts and Their Overlayer Permeability".ACS CATALYSIS (2024):9.