Na/Mo co-doped PbTiO<sub>3</sub> for photocatalytic water oxidation and Z-scheme overall water splitting under visible light

doi:10.1039/d4cc01761g

IMR OpenIR

	Na/Mo co-doped PbTiO₃ for photocatalytic water oxidation and Z-scheme overall water splitting under visible light
	Qi, Haozhi 1,2; Kang, Yuyang 1,2; Qiu, Jianhang 1,2; Zhang, Wenyu 1,2; Ma, Shangyi 1,2; Wang, Lianzhou 3,4; Liu, Gang 1,2
通讯作者	Kang, Yuyang(yykang@imr.ac.cn) ; Liu, Gang(gangliu@imr.ac.cn)
	2024-06-11
发表期刊	CHEMICAL COMMUNICATIONS
ISSN	1359-7345
卷号	60 期号:48 页码:6198-6201
摘要	Herein, we demonstrate a sodium/molybdenum (Na/Mo) co-doped ferroelectric PbTiO3 for efficient photocatalysis under visible light. Doped with a high concentration of Mo6+, quasi-continuous new energy levels are successfully introduced below the conduction band minimum of PbTiO3, giving rise to a band-to-band redshift of the absorption edge. The valence state difference of Mo6+ and Ti4+ in the doped PbTiO3 is compensated by the Na dopant, thus effectively suppressing the formation of the recombination centres caused by Mo4+. Combined with the intrinsic built-in electric field in PbTiO3, this Na/Mo co-doping strategy enables PbTiO3 to exhibit superior water oxidation activity under visible light with threshold wavelength up to 550 nm, which also promotes overall water splitting under visible light in a Z-scheme photocatalytic system. This strategy provides a generally applicable solution to extend the visible light absorption spectrum and engineer electronic structures of ferroelectric materials for photocatalysis and other energy conversion applications.
资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; CAS Projects for Young Scientists in Basic Research ; New Cornerstone Science Foundation through the XPLORER PRIZE
DOI	10.1039/d4cc01761g
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52425201] ; National Natural Science Foundation of China[52120105003] ; National Natural Science Foundation of China[52372243] ; National Key R&D Program of China[2021YFA1500800] ; CAS Projects for Young Scientists in Basic Research[YSBR-004] ; New Cornerstone Science Foundation through the XPLORER PRIZE
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001233463500001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/186670
专题	中国科学院金属研究所
通讯作者	Kang, Yuyang; Liu, Gang
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Univ Queensland, Nanomat Ctr, Sch Chem Engn, Brisbane, Qld 4072, Australia 4.Univ Queensland, AIBN, Brisbane, Qld 4072, Australia
推荐引用方式 GB/T 7714	Qi, Haozhi,Kang, Yuyang,Qiu, Jianhang,et al. Na/Mo co-doped PbTiO₃ for photocatalytic water oxidation and Z-scheme overall water splitting under visible light[J]. CHEMICAL COMMUNICATIONS,2024,60(48):6198-6201.
APA	Qi, Haozhi.,Kang, Yuyang.,Qiu, Jianhang.,Zhang, Wenyu.,Ma, Shangyi.,...&Liu, Gang.(2024).Na/Mo co-doped PbTiO₃ for photocatalytic water oxidation and Z-scheme overall water splitting under visible light.CHEMICAL COMMUNICATIONS,60(48),6198-6201.
MLA	Qi, Haozhi,et al."Na/Mo co-doped PbTiO₃ for photocatalytic water oxidation and Z-scheme overall water splitting under visible light".CHEMICAL COMMUNICATIONS 60.48(2024):6198-6201.