Sub-millisecond lithiothermal synthesis of graphitic meso-microporous carbon

doi:10.1038/s41467-024-47916-y

IMR OpenIR

	Sub-millisecond lithiothermal synthesis of graphitic meso-microporous carbon
	Zhang, Huimin 1; Qiu, Jingyi 1; Pang, Jie 2; Cao, Gaoping 1; Zhang, Bingsen 3; Wang, Li 4; He, Xiangming 4; Feng, Xuning 4; Ma, Shizhou 1; Zhang, Xinggao 1; Ming, Hai 1; Li, Zhuangnan 5; Li, Feng 3; Zhang, Hao 1
通讯作者	Li, Feng(fli@imr.ac.cn) ; Zhang, Hao(dr.h.zhang@hotmail.com)
	2024-04-25
发表期刊	NATURE COMMUNICATIONS
卷号	15 期号:1 页码:9
摘要	Porous carbons with concurrently high specific surface area and electronic conductivity are desirable by virtue of their desirable electron and ion transport ability, but conventional preparing methods suffer from either low yield or inferior quality carbons. Here we developed a lithiothermal approach to bottom-up synthesize highly meso-microporous graphitized carbon (MGC). The preparation can be finished in a few milliseconds by the self-propagating reaction between polytetrafluoroethylene powder and molten lithium (Li) metal, during which instant ultra-high temperature (>3000 K) was produced. This instantaneous carbon vaporization and condensation at ultra-high temperatures and in ultra-short duration enable the MGC to show a highly graphitized and continuously cross-coupled open pore structure. MGC displays superior electrochemical capacitor performance of exceptional power capability and ultralong-term cyclability. The processes used to make this carbon are readily scalable to industrial levels.
资助者	Funders: The Natural Science Foundation of China Grant Reference Number (22075320 and 52202336y ; Natural Science Foundation of China
DOI	10.1038/s41467-024-47916-y
收录类别	SCI
语种	英语
资助项目	Funders: The Natural Science Foundation of China Grant Reference Number (22075320 and 52202336y[22075320] ; Funders: The Natural Science Foundation of China Grant Reference Number (22075320 and 52202336y[52202336] ; Natural Science Foundation of China
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:001211008800021
出版者	NATURE PORTFOLIO
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/187267
专题	中国科学院金属研究所
通讯作者	Li, Feng; Zhang, Hao
作者单位	1.Res Inst Chem Def, Beijing Key Lab Adv Chem Energy Storage Technol &, Beijing, Peoples R China 2.Henan Univ, Sch Energy Sci & Technol, Zhengzhou, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China 4.Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing, Peoples R China 5.Univ Cambridge, Dept Mat Sci & Met, Cambridge, England
推荐引用方式 GB/T 7714	Zhang, Huimin,Qiu, Jingyi,Pang, Jie,et al. Sub-millisecond lithiothermal synthesis of graphitic meso-microporous carbon[J]. NATURE COMMUNICATIONS,2024,15(1):9.
APA	Zhang, Huimin.,Qiu, Jingyi.,Pang, Jie.,Cao, Gaoping.,Zhang, Bingsen.,...&Zhang, Hao.(2024).Sub-millisecond lithiothermal synthesis of graphitic meso-microporous carbon.NATURE COMMUNICATIONS,15(1),9.
MLA	Zhang, Huimin,et al."Sub-millisecond lithiothermal synthesis of graphitic meso-microporous carbon".NATURE COMMUNICATIONS 15.1(2024):9.