Tailoring electromagnetic wave absorption properties of M-type barium ferrite through Nd3+-(Nb5+/Ta5+) cosubstitution

doi:10.1016/j.mtcomm.2024.109378

IMR OpenIR

	Tailoring electromagnetic wave absorption properties of M-type barium ferrite through Nd³⁺-(Nb⁵⁺/Ta⁵⁺) cosubstitution
	Wei, Haoshan 1; Huang, Zhongxin 1; Cui, Jiewu 1; Zhang, Pengjie 2; Ma, Song 3; Sun, Wei 2; Liang, Xiaohui 4; Zhang, Yong 1; Wu, Yucheng 1
通讯作者	Cui, Jiewu(jwcui@hfut.edu.cn) ; Zhang, Yong(zhangyong.mse@hfut.edu.cn) ; Wu, Yucheng(ycwu@hfut.edu.cn)
	2024-06-01
发表期刊	MATERIALS TODAY COMMUNICATIONS
卷号	39 页码:15
摘要	M-type barium ferrites (Ba1-xNdxFe12-xMxO19, x = 0-0.3) with Nd3+-M5+ (M = Nb5+ and Ta5+) ions substituting Ba2+ and Fe3+ ions were prepared via a solid-state reaction. The crystalline phases, microstructure, magnetic properties, and electromagnetic wave absorption of the ion-substituted M-type barium ferrites were investigated. The saturation magnetization strength and coercivity changed with increasing substitution ratio x. The substitution of Nd-Nb and Nd-Ta ions reduced the anisotropic field of the material, thus lowering the natural resonant frequency. The complex permittivity of the ion-substituted samples was enhanced compared with that of the unsubstituted samples. Interfacial polarization, dipole polarization and dipole relaxation were induced by the substituted ions. The multiple natural resonances contributed by the numerous g-factors generated by Fe3+ ions and the exchange coupling among Fe3+, Fe2+, and O2- ions controlled the permeability of M-type barium ferrite, which broadened the effective absorption bandwidth. The excellent complex permittivity and complex permeability enabled the substituted samples to attain high attenuation constants and better impedance-matching properties. Hence, a strong reflection loss of (-35)-(-50) dB, an ultrabroad bandwidth of similar to 13.5 GHz, and a low matching thickness of < 0.75 mm were obtained in the frequency range of 26.5-40 GHz. The electromagnetic wave absorption was also improved in the frequency range of 2-18 GHz, where the samples with the substitution ratio of x = 0.1 exhibited relatively good performance with small matching thickness (<1.5 mm). Thereby, Nd-Nb and Nd-Ta substituted M-type barium ferrites are prospective candidates that can be used as an excellent microwave absorber material in the centimeter and millimeter wavelength frequency range.
关键词	M-type barium ferrites Microwave absorber material Ion cosubstitution Multiple natural resonances Ultrabroad bandwidth
资助者	National Key R & D Projects of China ; Tianchang-HFUT Industrial Innovation Projects
DOI	10.1016/j.mtcomm.2024.109378
收录类别	SCI
语种	英语
资助项目	National Key R & D Projects of China[2022YFB3504804] ; Tianchang-HFUT Industrial Innovation Projects[JZ2020YDZJ0004]
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:001249421400001
出版者	ELSEVIER
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/187298
专题	中国科学院金属研究所
通讯作者	Cui, Jiewu; Zhang, Yong; Wu, Yucheng
作者单位	1.Hefei Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat & Devices Anhui Prov, Hefei 230009, Peoples R China 2.BGRIMM Technol Grp Co Ltd, Beijing 102600, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Hangzhou Dianzi Univ, Hangzhou 310018, Peoples R China
推荐引用方式 GB/T 7714	Wei, Haoshan,Huang, Zhongxin,Cui, Jiewu,et al. Tailoring electromagnetic wave absorption properties of M-type barium ferrite through Nd³⁺-(Nb⁵⁺/Ta⁵⁺) cosubstitution[J]. MATERIALS TODAY COMMUNICATIONS,2024,39:15.
APA	Wei, Haoshan.,Huang, Zhongxin.,Cui, Jiewu.,Zhang, Pengjie.,Ma, Song.,...&Wu, Yucheng.(2024).Tailoring electromagnetic wave absorption properties of M-type barium ferrite through Nd³⁺-(Nb⁵⁺/Ta⁵⁺) cosubstitution.MATERIALS TODAY COMMUNICATIONS,39,15.
MLA	Wei, Haoshan,et al."Tailoring electromagnetic wave absorption properties of M-type barium ferrite through Nd³⁺-(Nb⁵⁺/Ta⁵⁺) cosubstitution".MATERIALS TODAY COMMUNICATIONS 39(2024):15.