2D crumpled nitrogen-doped carbon nanosheets anode with capacitive-dominated behavior for ultrafast-charging and high-energy-density Li-ion capacitors

doi:10.1039/d4ta02681k

IMR OpenIR

	2D crumpled nitrogen-doped carbon nanosheets anode with capacitive-dominated behavior for ultrafast-charging and high-energy-density Li-ion capacitors
	Liu, Fangyan 1; Yu, Tong 2; Qin, Jieqiong 3; Zhang, Liangzhu 1; Zhou, Feng 1; Zhang, Xiong 4,5,6; Ma, Yanwei 4,5,6; Li, Feng 2; Wu, Zhong-Shuai 1
通讯作者	Qin, Jieqiong(qinjieqiong@henau.edu.cn) ; Li, Feng(fli@imr.ac.cn) ; Wu, Zhong-Shuai(wuzs@dicp.ac.cn)
	2024-07-16
发表期刊	JOURNAL OF MATERIALS CHEMISTRY A
ISSN	2050-7488
卷号	12 期号:28 页码:17327-17337
摘要	Li-ion capacitors (LICs) are promising to simultaneously achieve battery-level energy density and supercapacitor-level power density, but the slow kinetics of diffusion-controlled battery anodes lead to unmatched two-electrode kinetics at the device level. Herein, we report a capacitive-dominated anode of two-dimensional (2D) crumpled nitrogen-doped carbon nanosheets (N-CNS) with tailored nitrogen incorporation and abundant mesopore distribution, exhibiting large capacities and superior rate performance. The optimized N-CNS delivers large reversible capacities of 620 and 121 mA h g-1 at 0.1 and 100 A g-1, respectively. The introduced nitrogen is found to contribute to providing additional pseudocapacity and high Li+ diffusion coefficients in the medium-high voltage region and enhancing the capacitive-dominated charge storage process. The structural reversibility and "adsorption-intercalation" mechanism are supported by in situ and ex situ measurements. Furthermore, it is theoretically revealed that N-CNS with superior electrochemical properties benefits from the increase in Li+ adsorption energy and the decline in the Li+ diffusion barrier. A LIC coupling the N-CNS anode with a porous carbon cathode outputs a high energy density of 75 W h kg-1 at an ultrahigh power density of 65 kW kg-1. This study provides a novel and effective approach to developing high-performance carbon-based anodes for constructing advanced LICs featuring high energy and power density. The synergistic effect of abundant mesopore distribution and nitrogen doping enables 2D crumpled nitrogen-doped carbon nanosheets as anode materials for Li-ion capacitors with large capacitive-capacities and ultrahigh rate performance.
资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; Transformational Technologies for Clean Energy and Demonstration Strategic Priority Research Program of the Chinese Academy of Sciences ; Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS ; DICP ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy (YLU-DNL Fund)
DOI	10.1039/d4ta02681k
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[22125903] ; National Natural Science Foundation of China[22005298] ; National Key R&D Program of China[2022YFA1504100] ; Transformational Technologies for Clean Energy and Demonstration Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21000000] ; Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS[DNL202016] ; Dalian National Laboratory For Clean Energy (DNL), CAS, DNL Cooperation Fund, CAS[DNL202019] ; DICP[DICP I2020032] ; DICP[DICP I202222] ; Joint Fund of the Yulin University ; Dalian National Laboratory for Clean Energy (YLU-DNL Fund)[2021002] ; Dalian National Laboratory for Clean Energy (YLU-DNL Fund)[2021009]
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号	WOS:001248956300001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/187325
专题	中国科学院金属研究所
通讯作者	Qin, Jieqiong; Li, Feng; Wu, Zhong-Shuai
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Henan Agr Univ, Coll Life Sci, 63 Agr Rd, Zhengzhou 450002, Peoples R China 4.Chinese Acad Sci, Inst Elect Engn, Beijing 100190, Peoples R China 5.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China 6.Inst Elect Engn & Adv Electromagnet Drive Technol, Qilu Zhongke, Jinan 250013, Peoples R China
推荐引用方式 GB/T 7714	Liu, Fangyan,Yu, Tong,Qin, Jieqiong,et al. 2D crumpled nitrogen-doped carbon nanosheets anode with capacitive-dominated behavior for ultrafast-charging and high-energy-density Li-ion capacitors[J]. JOURNAL OF MATERIALS CHEMISTRY A,2024,12(28):17327-17337.
APA	Liu, Fangyan.,Yu, Tong.,Qin, Jieqiong.,Zhang, Liangzhu.,Zhou, Feng.,...&Wu, Zhong-Shuai.(2024).2D crumpled nitrogen-doped carbon nanosheets anode with capacitive-dominated behavior for ultrafast-charging and high-energy-density Li-ion capacitors.JOURNAL OF MATERIALS CHEMISTRY A,12(28),17327-17337.
MLA	Liu, Fangyan,et al."2D crumpled nitrogen-doped carbon nanosheets anode with capacitive-dominated behavior for ultrafast-charging and high-energy-density Li-ion capacitors".JOURNAL OF MATERIALS CHEMISTRY A 12.28(2024):17327-17337.