Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts

doi:10.1002/cctc.202400449

IMR OpenIR

	Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts
	Wang, Di 1,2; Lu, Xingyu 2,3; Xu, Haiyan 1; Dou, Jing 2,3; Zhang, Xuefei 4; Xie, Zailai 4; Qi, Wei 2,3
通讯作者	Xu, Haiyan(xhy1020@gmail.com) ; Xie, Zailai(zlxie@fzu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn)
	2024-07-09
发表期刊	CHEMCATCHEM
ISSN	1867-3880
页码	9
摘要	5-Hydroxymethylfurfural (HMF) is a widely used biomass platform chemical that plays a crucial role in bridging biomass and fossil resources. Electrocatalytic oxidation of HMF provides an efficient way to obtain high-value-added biomass-derived chemicals, among which the intermediate product 5-formyl-2-furan carboxylic acid (FFCA) has attracted considerable attention. However, the weak adsorption ability of monometallic nickel oxide (NiOx) to HMF in neutral electrolyte restricts its further development, resulting in low HMF conversion and FFCA yield. In this study, we successfully constructed a novel nickel oxide-platinum oxide hybrid catalyst supported on carbon felt (NiOx-PtOx/CF), which exhibits an optimized adsorption ability of HMF, leading to the outstanding FFCA yield up to 77 % in the neutral media. The high activity of the NiOx-PtOx/CF catalyst can be attributed to the redistribution of the electrons and the optimization of the electronic structure on the Ni active site due to the introduction of PtOx on NiOx nanosheets. This study offers valuable insights for the design of efficient multicomponent electrocatalysts for electrocatalytic biomass refinery systems. Highly efficient of HMF into FFCA on a NiOx-PtOx/carbon felt composite electrode is achieved at a potential of 1.78 VRHE with high value product of FFCA yield up to 77 %. The high activity of the NiOx-PtOx/CF catalyst can be attributed to the redistribution of the electrons and the optimization of the electronic structure on the Ni active site due to the introduction of PtOx on NiOx nanosheets. image
关键词	Electrooxidation 5-hydroxymethylfurfural formyl-2-furancarboxylic acid bimetallic catalysts electronic regulation
资助者	NSFC of China ; Shccig-Qinling Program ; China Baowu Low Carbon Metallurgy Innovation Foundation ; IMR Innovation Fund
DOI	10.1002/cctc.202400449
收录类别	SCI
语种	英语
资助项目	NSFC of China[22072163] ; NSFC of China[U23A20545] ; Shccig-Qinling Program ; China Baowu Low Carbon Metallurgy Innovation Foundation[BWLCF202113] ; IMR Innovation Fund[2023-PY13]
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:001264896100001
出版者	WILEY-V C H VERLAG GMBH
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/188093
专题	中国科学院金属研究所
通讯作者	Xu, Haiyan; Xie, Zailai; Qi, Wei
作者单位	1.Shenyang Pharmaceut Univ, Sch Pharm, 26 Huatuo Rd,High & New Tech Dev Zone, Benxi 117004, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 4.Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350016, Peoples R China
推荐引用方式 GB/T 7714	Wang, Di,Lu, Xingyu,Xu, Haiyan,et al. Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts[J]. CHEMCATCHEM,2024:9.
APA	Wang, Di.,Lu, Xingyu.,Xu, Haiyan.,Dou, Jing.,Zhang, Xuefei.,...&Qi, Wei.(2024).Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts.CHEMCATCHEM,9.
MLA	Wang, Di,et al."Selective Synthesis of Formyl-2-Furancarboxylic Acid via Enhanced Adsorption of 5-Hydroxymethylfurfural on Composite Catalysts".CHEMCATCHEM (2024):9.