Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries

doi:10.1021/acs.nanolett.4c00693

IMR OpenIR

	Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries
	Peng, Zhi 1; Yan, Hui 2; Zhang, Qingqing 1; Liu, Shude 5; Jun, Seong Chan 3; Poznyak, Sergey 4; Guo, Na 1; Li, Yuehua 1; Tian, Huajun 6,7,8; Dai, Lei 1; Wang, Ling 1; He, Zhangxing 1
通讯作者	Liu, Shude(sdliu@dhu.edu.cn) ; Tian, Huajun(Huajun.Tian@ncepu.edu.cn) ; He, Zhangxing(zxhe@ncst.edu.cn)
	2024-07-22
发表期刊	NANO LETTERS
ISSN	1530-6984
卷号	24 期号:30 页码:9137-9146
摘要	Uncontrollable dendrite growth and corrosion induced by reactive water molecules and sulfate ions (SO42-) seriously hindered the practical application of aqueous zinc ion batteries (AZIBs). Here we construct artificial solid electrolyte interfaces (SEIs) realized by sodium and calcium bentonite with a layered structure anchored to anodes (NB@Zn and CB@Zn). This artificial SEI layer functioning as a protective coating to isolate activated water molecules, provides high-speed transport channels for Zn2+, and serves as an ionic sieve to repel negatively charged anions while attracting positively charged cations. The theoretical results show that the bentonite electrodes exhibit a higher binding energy for Zn2+. This demonstrates that the bentonite protective layer enhances the Zn-ion deposition kinetics. Consequently, the NB@Zn//MnO2 and CB@Zn//MnO2 full-battery capacities are 96.7 and 70.4 mAh g(-1) at 2.0 A g(-1) after 1000 cycles, respectively. This study aims to stabilize Zn anodes and improve the electrochemical performance of AZIBs by ion-selection sieving.
关键词	aqueous Zn-ion batteries anode protectivelayer layered clay ion selection sieving
资助者	National Natural Science Foundation of China ; Hebei Natural Science Fund for Distinguished Young Scholar ; Youth Talent Program of Hebei Provincial Education Department ; Natural Science Foundation of Hebei Province ; Science and Technology Project of Hebei Education Department ; National Research Foundation of Korea (NRF) - Korea government (MIST) ; Technology Innovation Program - Ministry of Trade, Industry & Energy (MOTIE, Korea) ; Beijing Laboratory of New Energy Storage Technology (North China Electric Power University) ; Program of the National Energy Storage Industry-Education Platform
DOI	10.1021/acs.nanolett.4c00693
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51872090] ; National Natural Science Foundation of China[51772097] ; National Natural Science Foundation of China[52302223] ; Hebei Natural Science Fund for Distinguished Young Scholar[E2019209433] ; Youth Talent Program of Hebei Provincial Education Department[BJ2018020] ; Natural Science Foundation of Hebei Province[E2020209151] ; Natural Science Foundation of Hebei Province[E2022209158] ; Science and Technology Project of Hebei Education Department[SLRC2019028] ; National Research Foundation of Korea (NRF) - Korea government (MIST)[NRF-2019R1A2C2090443] ; Technology Innovation Program - Ministry of Trade, Industry & Energy (MOTIE, Korea)[20013621] ; Beijing Laboratory of New Energy Storage Technology (North China Electric Power University) ; Program of the National Energy Storage Industry-Education Platform
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:001274536900001
出版者	AMER CHEMICAL SOC
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/188458
专题	中国科学院金属研究所
通讯作者	Liu, Shude; Tian, Huajun; He, Zhangxing
作者单位	1.North China Univ Sci & Technol, Sch Chem Engn, Tangshan 063009, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110000, Peoples R China 3.Yonsei Univ, Sch Mech Engn, Seoul 120749, South Korea 4.Belarusian State Univ, Res Inst Phys Chem Problems, Minsk 220030, BELARUS 5.Donghua Univ, Coll Text, Shanghai Frontiers Sci Ctr Adv Text, Shanghai 201620, Peoples R China 6.North China Elect Power Univ, Key Lab Power Stn Energy Transfer Convers & Syst, Minist Educ, Beijing 102206, Peoples R China 7.North China Elect Power Univ, Sch Energy Power & Mech Engn, Beijing 102206, Beijing, Peoples R China 8.North China Elect Power Univ, Beijing Lab New Energy Storage Technol, Beijing 102206, Peoples R China
推荐引用方式 GB/T 7714	Peng, Zhi,Yan, Hui,Zhang, Qingqing,et al. Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries[J]. NANO LETTERS,2024,24(30):9137-9146.
APA	Peng, Zhi.,Yan, Hui.,Zhang, Qingqing.,Liu, Shude.,Jun, Seong Chan.,...&He, Zhangxing.(2024).Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries.NANO LETTERS,24(30),9137-9146.
MLA	Peng, Zhi,et al."Stabilizing Zinc Anode through Ion Selection Sieving for Aqueous Zn-Ion Batteries".NANO LETTERS 24.30(2024):9137-9146.