| Highly efficient mechanocaloric cooling using colossal barocaloric plastic crystals | |
| Qian, Kun1; Lin, Shangchao1; Zhang, Zhe2; Li, Bing2; Peng, Yichao1; Li, Yijin1; Zhao, Changying1 | |
| 通讯作者 | Lin, Shangchao(shangchaolin@sjtu.edu.cn) ; Li, Bing(bingli@imr.ac.cn) ; Zhao, Changying(changying.zhao@sjtu.edu.cn) |
| 2024-06-19 | |
| 发表期刊 | CELL REPORTS PHYSICAL SCIENCE
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| 卷号 | 5期号:6页码:21 |
| 摘要 | Despite the emergence of colossal barocaloric materials with great potential to replace environmentally unfriendly vapor-compression refrigerants, a scalable and cyclic reversible cooling device has not been demonstrated yet. Here, we develop experimental compressive mechanocaloric prototypes using bulk amounts of low-cost plastic crystal neopentylglycol (NPG) with high device-level scalability. Large quasi-adiabatic temperature changes in NPG of 20.8 K for heating and- 16.7 K for cooling are achieved during the cyclic pressurization-depressurization processes from ambient pressure to 231 MPa. A maximum temperature drop of 3.8 K and cooling energy of 900 J in water as the heat-exchanging medium are observed in the prototype. Using molecular dynamics simulations, an outstanding coefficient of performance of 14 and cooling energy density of 90 kJ/kg are achieved for the reverse Stirling cooling cycle at a large temperature span of 5 K, while the corresponding values are 7.5 and 30 kJ/kg for the reverse Brayton cooling cycle. |
| 资助者 | National Natural Science Foundation of China ; Thousand Young Talents Program of China ; Key Research Program of Frontier Sciences of Chinese Academy of Sciences ; Ministry of Science and Technology of the People's Republic of China |
| DOI | 10.1016/j.xcrp.2024.101981 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China[52276076] ; National Natural Science Foundation of China[11804346] ; Thousand Young Talents Program of China[BE0200006] ; Key Research Program of Frontier Sciences of Chinese Academy of Sciences[ZDBS-LY-JSC002] ; Ministry of Science and Technology of the People's Republic of China[2020YFA0406002] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
| WOS类目 | Chemistry, Multidisciplinary ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Multidisciplinary |
| WOS记录号 | WOS:001293747000001 |
| 出版者 | CELL PRESS |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.imr.ac.cn/handle/321006/189031 |
| 专题 | 中国科学院金属研究所 |
| 通讯作者 | Lin, Shangchao; Li, Bing; Zhao, Changying |
| 作者单位 | 1.Shanghai Jiao Tong Univ, Inst Engn Thermophys, Sch Mech Engn, Key Lab Power Machinery & Engn,Minist Educ, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qian, Kun,Lin, Shangchao,Zhang, Zhe,et al. Highly efficient mechanocaloric cooling using colossal barocaloric plastic crystals[J]. CELL REPORTS PHYSICAL SCIENCE,2024,5(6):21. |
| APA | Qian, Kun.,Lin, Shangchao.,Zhang, Zhe.,Li, Bing.,Peng, Yichao.,...&Zhao, Changying.(2024).Highly efficient mechanocaloric cooling using colossal barocaloric plastic crystals.CELL REPORTS PHYSICAL SCIENCE,5(6),21. |
| MLA | Qian, Kun,et al."Highly efficient mechanocaloric cooling using colossal barocaloric plastic crystals".CELL REPORTS PHYSICAL SCIENCE 5.6(2024):21. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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