Effects of nitrogen content on the phase composition and high-temperature steam oxidation resistance of Cr 0.5 Al 0.5 N x (x=0.33, 0.81, 1.23) coatings on Zry-4 alloy

doi:10.1016/j.surfcoat.2024.131004

IMR OpenIR

	Effects of nitrogen content on the phase composition and high-temperature steam oxidation resistance of Cr _0.5 Al_0.5 N _x (x=0.33, 0.81, 1.23) coatings on Zry-4 alloy
	Zhang, Yi 1,2; Wang, Wenting 1,2; Li, Jingjing 3; Li, Yang 1,2; Ma, Ke 2; Xu, Jingjun 2; Wang, Xin 4; Zuo, Jun 2; Zhu, Pengli 2; Li, Meishuan 2
通讯作者	Xu, Jingjun(jjxu@imr.ac.cn)
	2024-07-15
发表期刊	SURFACE & COATINGS TECHNOLOGY
ISSN	0257-8972
卷号	487 页码:13
摘要	Cr0.5Al0.5Nx (x = 0.33, 0.81, 1.23) coatings were deposited on Zry-4 alloy using magnetron reaction sputtering technique to investigate their application as accident-tolerant fuel materials. The effects of nitrogen (N) content on the phase composition and high-temperature steam oxidation resistance of the coatings were systematically investigated. With the increasing N content, the phase composition of the coatings is mainly transformed from Cr(Al) to the cubic-CrAlN phase, which may be due to the formation of a greater number of CrN bonds and AlN bonds. The high-N content of the Cr0.5Al0.5Nx coating can significantly enhance the high-temperature steam oxidation resistance of zirconium alloy. Compared to the bare Zr alloy, the weight gain oxidation of the Cr0.5Al0.5N1.23 coating is reduced by 45 % after oxidation at 1200 degrees C for 1 h. The oxide layer thickness of the bare Zry-4 alloy is as high as 350 mu m, while the oxide layer thickness of the Cr0.5Al0.5N1.23 coating is only about 12 mu m. The complex oxide layer structure and an internal continuous Al2O3 layer are formed, effectively preventing the inward diffusion of O2-. In addition, with the increase of N content in the coatings, the degree of interdiffusion between the coating and the substrate is weakened. The formation of alpha-Zr(N) layer in the Cr0.5Al0.5N1.23 coating significantly inhibits the interdiffusion between the coating and the substrate.
关键词	Cr (0.5) Al- 0.5 N (x) Nitrogen content High-temperature steam oxidation Accident-tolerant fuel Magnetron sputtering
资助者	National Natural Science Foundation of China
DOI	10.1016/j.surfcoat.2024.131004
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52071318]
WOS研究方向	Materials Science ; Physics
WOS类目	Materials Science, Coatings & Films ; Physics, Applied
WOS记录号	WOS:001299877200001
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/189413
专题	中国科学院金属研究所
通讯作者	Xu, Jingjun
作者单位	1.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Shenyang Ligong Univ, Sch Mat Sci & Engn, Shenyang 110159, Peoples R China 4.Northwest Inst Nonferrous Met Res, Xian 710016, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Yi,Wang, Wenting,Li, Jingjing,et al. Effects of nitrogen content on the phase composition and high-temperature steam oxidation resistance of Cr _0.5 Al_0.5 N _x (x=0.33, 0.81, 1.23) coatings on Zry-4 alloy[J]. SURFACE & COATINGS TECHNOLOGY,2024,487:13.
APA	Zhang, Yi.,Wang, Wenting.,Li, Jingjing.,Li, Yang.,Ma, Ke.,...&Li, Meishuan.(2024).Effects of nitrogen content on the phase composition and high-temperature steam oxidation resistance of Cr _0.5 Al_0.5 N _x (x=0.33, 0.81, 1.23) coatings on Zry-4 alloy.SURFACE & COATINGS TECHNOLOGY,487,13.
MLA	Zhang, Yi,et al."Effects of nitrogen content on the phase composition and high-temperature steam oxidation resistance of Cr _0.5 Al_0.5 N _x (x=0.33, 0.81, 1.23) coatings on Zry-4 alloy".SURFACE & COATINGS TECHNOLOGY 487(2024):13.