| A Roadmap for Ferroelectric-Antiferroelectric Phase Transition | |
| Jiang, Ru-Jian1,2; Tang, Yun-Long1,2; Liu, Su-Zhen1,2; Zhu, Mei-Xiong1,2; Li, Changji1; Feng, Yan-Peng3,4; Gong, Feng-Hui3,5; Wang, Jing-Hui1,2; Lv, Xiao-Dong1,2; Chen, Shuang-Jie1,2; Wang, Yu-Jia1,2; Zhu, Yin-Lian3,6; Ma, Xiu-Liang3,4,5 | |
| 通讯作者 | Tang, Yun-Long(yltang@imr.ac.cn) ; Zhu, Yin-Lian(zhuyinlian@sslab.org.cn) |
| 2024-09-06 | |
| 发表期刊 | NANO LETTERS
 |
| ISSN | 1530-6984 |
| 卷号 | 24期号:37页码:11714-11721 |
| 摘要 | Antiferroelectric materials have shown great potential in electronic devices benefiting from the reversible phase transition between ferroelectric and antiferroelectric phases. Understanding the dipole arrangements and clear phase transition pathways is crucial for design of antiferroelectric materials-based energy storage and conversion devices. However, the specific phase transition details remain largely unclear and even controversial to date. Here, we have grown a series of PbZrO3 on SrTiO3 substrates and elucidated the fine atom structures and phase transition pathways using atomic-resolution transmission electron microscopy. Specifically, a roadmap for ferroelectric to antiferroelectric phase transitions, here with increasing film thickness, is determined as ferroelectric rhombohedral (R3c)-ferroelectric monoclinic (Pc)-ferrielectric orthorhombic (Ima2)-antiferroelectric orthorhombic (Pbam), where Pc and Ima2 phases act as structural bridges. Moreover, the phase transition pathway is strongly related to the synergistic effect of oxygen octahedral tilting and cation displacement. These findings provide an insightful understanding for the theories and related properties of antiferroelectrics. |
| 关键词 | antiferroelectric lead zirconate phase transition oxygen octahedral atomic-scale |
| 资助者 | National Natural Science Foundation of China ; IMR Innovation Fund ; Guangdong Provincial Quantum Science Strategic Initiative ; Shenyang National Laboratory for Materials Science ; Youth Innovation Promotion Association CAS ; Guangdong Basic and Applied Basic Research Foundation ; China National Postdoctoral Program for Innovative Talents ; China Postdoctoral Science Foundation |
| DOI | 10.1021/acs.nanolett.4c03382 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China[51971223] ; National Natural Science Foundation of China[52122101] ; IMR Innovation Fund[2024-ZD01] ; Guangdong Provincial Quantum Science Strategic Initiative[GDZX2202001] ; Guangdong Provincial Quantum Science Strategic Initiative[GDZX2302001] ; Shenyang National Laboratory for Materials Science[L2022R04] ; Youth Innovation Promotion Association CAS[2021187] ; Guangdong Basic and Applied Basic Research Foundation[2023A1515011058] ; China National Postdoctoral Program for Innovative Talents[BX20240245] ; China Postdoctoral Science Foundation[2024M752303] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| WOS记录号 | WOS:001308693500001 |
| 出版者 | AMER CHEMICAL SOC |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.imr.ac.cn/handle/321006/189781 |
| 专题 | 中国科学院金属研究所 |
| 通讯作者 | Tang, Yun-Long; Zhu, Yin-Lian |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Songshan Lake Mat Lab, Bay Area Ctr Electron Microscopy, Dongguan 523808, Peoples R China 4.Quantum Sci Ctr Guangdong HongKong Macau Greater B, Shenzhen 518000, Peoples R China 5.Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China 6.Hunan Univ Sci & Technol, Sch Mat Sci & Engn, Xiangtan 411201, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Ru-Jian,Tang, Yun-Long,Liu, Su-Zhen,et al. A Roadmap for Ferroelectric-Antiferroelectric Phase Transition[J]. NANO LETTERS,2024,24(37):11714-11721. |
| APA | Jiang, Ru-Jian.,Tang, Yun-Long.,Liu, Su-Zhen.,Zhu, Mei-Xiong.,Li, Changji.,...&Ma, Xiu-Liang.(2024).A Roadmap for Ferroelectric-Antiferroelectric Phase Transition.NANO LETTERS,24(37),11714-11721. |
| MLA | Jiang, Ru-Jian,et al."A Roadmap for Ferroelectric-Antiferroelectric Phase Transition".NANO LETTERS 24.37(2024):11714-11721. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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