Atomically dispersed metal cocatalysts for solar energy conversion

doi:10.1039/d4ee03065f

IMR OpenIR

	Atomically dispersed metal cocatalysts for solar energy conversion
	Kong, Kejian 1; Zhang, Hao 2; Han, Ali 1,3; Li, Feng 2; Wang, Dingsheng 1
通讯作者	Han, Ali(hanali@mail.ustc.edu.cn) ; Li, Feng(li_feng@fudan.edu.cn) ; Wang, Dingsheng(wangdingsheng@mail.tsinghua.edu.cn)
	2024-09-04
发表期刊	ENERGY & ENVIRONMENTAL SCIENCE
ISSN	1754-5692
页码	32
摘要	The pursuit of clean and sustainable energy has become more urgent than ever. Photocatalysis is a potential approach to convert highly sustainable solar energy into promising fuels. Additionally, effective and robust cocatalysts are crucial factors in facilitating rapid photogenerated charge separation/charge transfer, widespread absorption and highly photoactive reactions and achieving efficient solar-to-chemical energy conversion. In this review, we summarize the recent advances in efficient cocatalysts provided with atomic metal sites, including single-atom metal cocatalysts (SAMCs) and atomic cluster metal cocatalysts (ACMCs). First, we present a general definition of atomic metal sites to improve our understanding of the structure-activity correlations at the atomic scale. Then, a brief description of advanced characterization techniques is given to distinguish the atomic metal sites. After introducing the atomic metal sites, regulating strategies for the enhancement of photocatalysis, such as electronic metal-support interaction (EMSI), atomic alloy strategy and confinement strategy, the advantages and disadvantages of each type of atomic metal sites and the solar energy conversion applications (water splitting, CO2 reduction, N2 reduction, etc.) are highlighted. Finally, the prospective and a summary of the comparison of different atomic metal sites as well as the potential development direction of photocatalysts in the future are outlined. This review explores the role of atomic metal site cocatalysts in photocatalysis for solar energy conversion, focusing on the recent advances in single-atom and atomic cluster cocatalysts, their structure-activity relationships, and key applications.
资助者	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fudan University ; Natural Science Foundation of Liaoning Province-Outstanding Youth Foundation
DOI	10.1039/d4ee03065f
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[QXH2203003] ; National Natural Science Foundation of China[22375048] ; National Natural Science Foundation of China[22202214] ; National Natural Science Foundation of China[JIH2203013Y] ; Fudan University[2022-YQ-02] ; Natural Science Foundation of Liaoning Province-Outstanding Youth Foundation
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology
WOS类目	Chemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences
WOS记录号	WOS:001316150800001
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/190141
专题	中国科学院金属研究所
通讯作者	Han, Ali; Li, Feng; Wang, Dingsheng
作者单位	1.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Fudan Univ, Lab Adv Mat, Shanghai Key Lab Mol Catalysis & Innovat Mat, 220 Handan, Shanghai 200433, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Kong, Kejian,Zhang, Hao,Han, Ali,et al. Atomically dispersed metal cocatalysts for solar energy conversion[J]. ENERGY & ENVIRONMENTAL SCIENCE,2024:32.
APA	Kong, Kejian,Zhang, Hao,Han, Ali,Li, Feng,&Wang, Dingsheng.(2024).Atomically dispersed metal cocatalysts for solar energy conversion.ENERGY & ENVIRONMENTAL SCIENCE,32.
MLA	Kong, Kejian,et al."Atomically dispersed metal cocatalysts for solar energy conversion".ENERGY & ENVIRONMENTAL SCIENCE (2024):32.