Edge functionalized with benzenesulfonyl groups of g-C<sub>3</sub>N<sub>4</sub> nanosheets as a highly efficient photocatalyst for water purification

doi:10.1016/j.jece.2024.114207

IMR OpenIR

	Edge functionalized with benzenesulfonyl groups of g-C₃N₄ nanosheets as a highly efficient photocatalyst for water purification
	Li, Xiangrong 1,2; Liu, Qiang 2,3; Xiao, Wen 4; An, Shuai 5; Xiao, Jun 2
通讯作者	Xiao, Jun(jxiao14b@imr.ac.cn)
	2024-12-01
发表期刊	JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
ISSN	2213-2929
卷号	12 期号:6 页码:11
摘要	Photocatalytic water purification is a promising method for environmental remediation, but it is greatly hindered by the rapid charge carrier recombination behavior of the photocatalysts. Herein, a simple wet-chemical method is developed for grafting electron-withdrawing benzenesulfonyl groups at the edges of g-C3N4 nanosheets. These exhibited a superior and versatile photocatalytic performance on the degradation of organic contaminant, as well as disinfected Escherichia coli (E. E. coli) ) bacteria under visible light illumination. Systematic studies reveal that the grafting of benzenesulfonyl groups led to the synergic effect in ultrathin g-C3N4 nanosheets of enhancing the photogenerated charge carrier separation on surface, improving light absorption, changing electronic band structure, and causing surface charge redistribution, all of which are beneficial for enhancing the photocatalytic performance. Notably, these edge-activated g-C3N4 photocatalysts also demonstrate remarkable photocatalytic activity in the real tap water and urban wastewater, indicating their promising potential for application in real wastewater treatment.
关键词	Metal-free photocatalysts Electron-withdrawing Charge carrier separation Wastewater treatment
资助者	Shenyang National Laboratory for Materials Science Youth programs
DOI	10.1016/j.jece.2024.114207
收录类别	SCI
语种	英语
资助项目	Shenyang National Laboratory for Materials Science Youth programs[E01SL917]
WOS研究方向	Engineering
WOS类目	Engineering, Environmental ; Engineering, Chemical
WOS记录号	WOS:001321826200001
出版者	ELSEVIER SCI LTD
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/190356
专题	中国科学院金属研究所
通讯作者	Xiao, Jun
作者单位	1.Liaoning Univ, Coll Light Ind, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 4.Third Peoples Hosp Hubei Prov, Wuhan 430000, Peoples R China 5.China Geol Survey, Shenyang Ctr Geol Survey, Shenyang 110032, Peoples R China
推荐引用方式 GB/T 7714	Li, Xiangrong,Liu, Qiang,Xiao, Wen,et al. Edge functionalized with benzenesulfonyl groups of g-C₃N₄ nanosheets as a highly efficient photocatalyst for water purification[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2024,12(6):11.
APA	Li, Xiangrong,Liu, Qiang,Xiao, Wen,An, Shuai,&Xiao, Jun.(2024).Edge functionalized with benzenesulfonyl groups of g-C₃N₄ nanosheets as a highly efficient photocatalyst for water purification.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,12(6),11.
MLA	Li, Xiangrong,et al."Edge functionalized with benzenesulfonyl groups of g-C₃N₄ nanosheets as a highly efficient photocatalyst for water purification".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 12.6(2024):11.