Redox Concomitant Formation Method for Fabrication of Cu(I)-MOF/Polymer Composites with Antifouling Properties

doi:10.1002/anie.202411539

IMR OpenIR

	Redox Concomitant Formation Method for Fabrication of Cu(I)-MOF/Polymer Composites with Antifouling Properties
	He, Wenxiu 1; Li, Xiangyu 2; Dai, Xueya 3; Shao, Lei 1; Fu, Yu 1; Xu, Dake 2; Qi, Wei 3
通讯作者	Fu, Yu(fuyu@mail.neu.edu.cn) ; Xu, Dake(xudake@mail.neu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn)
	2024-10-24
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
卷号	63 期号:44 页码:10
摘要	Marine biofouling, which is one of the technical challenges hindering the growth of the marine economy, has been controlled using cuprous oxide (Cu2O) nanoparticles due to the exceptional antifouling properties of Cu(I) ions. However, Cu2O nanoparticles have encountered bottlenecks due to explosive releases of Cu+ ions, high toxicity at elevated doses, and long-term instability. Here, we present a novel method called Redox Concomitant Formation (RCF) for fabricating a hierarchical Cu(I) metal-organic framework polypyrrole (Cu(I)-MOF/PPy) composite. This method enables in situ phase transition via successive redox reactions that change the chemical valence state and coordination mode of Cu(II)-MOF, resulting in a new structure of Cu(I)-MOF while creating a PPy layer surrounded by the hierarchical structure. Owing to the steady release of Cu+ ions from the Cu(I) sites and photothermal properties of PPy, Cu(I)-MOF/PPy exhibits superior and broad-spectrum resistance to marine bacteria, algae, and surface-adhered biofilms in complex biological environments, as well as long-term stability, resulting in 100 % eradication efficiency under solar-driven heating. Mechanistic insights into successive structural redox reactions and formation using the RCF method are provided in detail, enabling the fabrication of novel MOFs with the desired composition and structure for a wide range of potential applications.
关键词	Metal-organic frameworks Cu(I)-MOF/polymer composites photothermal effect antimicrobial antifouling
资助者	National Natural Science Foundation of China ; Open Project of State Key Laboratory of Supramolecular Structure and Materials ; National Key Research and Development Program of China
DOI	10.1002/anie.202411539
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm 202406] ; National Key Research and Development Program of China[2022YFB3808800] ; [U2006219]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001342073200024
出版者	WILEY-V C H VERLAG GMBH
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/191011
专题	中国科学院金属研究所
通讯作者	Fu, Yu; Xu, Dake; Qi, Wei
作者单位	1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 2.Northeastern Univ, Sch Mat Sci & Engn, Shenyang Natl Lab Mat Sci, Key Lab Anisotropy & Texture Mat,Minist Educ, Shenyang 110819, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	He, Wenxiu,Li, Xiangyu,Dai, Xueya,et al. Redox Concomitant Formation Method for Fabrication of Cu(I)-MOF/Polymer Composites with Antifouling Properties[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024,63(44):10.
APA	He, Wenxiu.,Li, Xiangyu.,Dai, Xueya.,Shao, Lei.,Fu, Yu.,...&Qi, Wei.(2024).Redox Concomitant Formation Method for Fabrication of Cu(I)-MOF/Polymer Composites with Antifouling Properties.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,63(44),10.
MLA	He, Wenxiu,et al."Redox Concomitant Formation Method for Fabrication of Cu(I)-MOF/Polymer Composites with Antifouling Properties".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 63.44(2024):10.