Oxide cathode materials NaxTMO<sub>2</sub> (TM = Mn, Ni, Fe) for sodium-ion batteries: A review of factors influencing multiphase formation and mechanisms of multiphase interactions

doi:10.1016/j.est.2024.114279

IMR OpenIR

	Oxide cathode materials NaxTMO₂ (TM = Mn, Ni, Fe) for sodium-ion batteries: A review of factors influencing multiphase formation and mechanisms of multiphase interactions
	Zhang, Yixuan 1; Liu, Guo-Qiang 1,2; Sun, Qiang 1; Qiao, Danlei 3; Chen, Jiaguan 1; Wen, Lei 4; Zhao, Meiju 5
通讯作者	Liu, Guo-Qiang(liugq@smm.neu.edu.cn)
	2024-11-20
发表期刊	JOURNAL OF ENERGY STORAGE
ISSN	2352-152X
卷号	102 页码:26
摘要	This paper provides a comprehensive overview of the most common structures and characteristics of monolithic Mn-based, binary Mn-Fe, Mn-Ni-based, and ternary Mn-Ni-Fe-based sodium ion oxide cathode materials. First, it summarizes the effects of Mn-Ni-Fe ratios, Na content, synthesis temperature, and dopant content and valence on the material phases, presenting these relationships in phase diagrams. Second, based on the cation potential theory, it calculates the effects of different dopant valence states, and predicts phase diagrams for various material systems under different dopant valence states. Finally, the paper summarizes several interfacial forms of multiphase combinations, illustrates the corresponding schematics, and elaborates on the "interlocking effect" in multiphase materials. This work paves the way for the design and development of high-performance multiphase sodium ion battery oxide cathode materials.
关键词	Sodium-ion batteries Oxide cathode Multiphase Dopant valence Phase diagram Interlocking effect
资助者	National Natural Science Foundation of China
DOI	10.1016/j.est.2024.114279
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[U23B20139]
WOS研究方向	Energy & Fuels
WOS类目	Energy & Fuels
WOS记录号	WOS:001340109300001
出版者	ELSEVIER
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/191018
专题	中国科学院金属研究所
通讯作者	Liu, Guo-Qiang
作者单位	1.Northeastern Univ, Sch Met, Key Lab Ecol Met Multimet Mineral, Minist Educ, Shenyang 110819, Peoples R China 2.Sichuan Vocat & Tech Coll, Suining 629000, Sichuan, Peoples R China 3.CRRC Qingdao Sifang Rolling Stock Res Inst Co LTD, Qingdao 266031, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 5.Shandong Tianhan New Energy Technol Co Ltd, Zaozhuang, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Yixuan,Liu, Guo-Qiang,Sun, Qiang,et al. Oxide cathode materials NaxTMO₂ (TM = Mn, Ni, Fe) for sodium-ion batteries: A review of factors influencing multiphase formation and mechanisms of multiphase interactions[J]. JOURNAL OF ENERGY STORAGE,2024,102:26.
APA	Zhang, Yixuan.,Liu, Guo-Qiang.,Sun, Qiang.,Qiao, Danlei.,Chen, Jiaguan.,...&Zhao, Meiju.(2024).Oxide cathode materials NaxTMO₂ (TM = Mn, Ni, Fe) for sodium-ion batteries: A review of factors influencing multiphase formation and mechanisms of multiphase interactions.JOURNAL OF ENERGY STORAGE,102,26.
MLA	Zhang, Yixuan,et al."Oxide cathode materials NaxTMO₂ (TM = Mn, Ni, Fe) for sodium-ion batteries: A review of factors influencing multiphase formation and mechanisms of multiphase interactions".JOURNAL OF ENERGY STORAGE 102(2024):26.