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An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor
W. L. Feng; L. C. Pu; X. Z. Yang; N. Hu
2011
发表期刊Journal of Magnetism and Magnetic Materials
ISSN0304-8853
卷号323期号:22页码:2828-2830
摘要In this paper, the nickel site, optical spectra and electron paramagnetic resonance (EPR) g factor of nickel-zinc phosphate glasses have been studied by ligand-field theory. The orbital mixing effect between p and d orbits has been included in the calculation by two-spin-orbit parameter model. The present study shows that nickel occupies the tetrahedral zinc site with cubic symmetry in nickel-zinc phosphate glasses. Unlike the result of previous study that assigns nickel to an octahedral interstitial site, it is an optional explanation for nickel sites in nickel-zinc phosphate glasses by analysing the optical absorption spectra and EPR g factor. (C) 2011 Elsevier B.V. All rights reserved.
部门归属[feng, w. l.; pu, l. c.; yang, x. z.; hu, n.] chongqing univ technol, dept appl phys, chongqing 400054, peoples r china. [feng, w. l.] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;feng, wl (reprint author), chongqing univ technol, dept appl phys, chongqing 400054, peoples r china;wenlinfeng@126.com
关键词Electron Paramagnetic Resonance (Epr) Ligand Field Theory Local Lattice Structure Glasses Spin-hamiltonian Parameters Atomic Screening Constants Scf Functions Centers Crystal Ni++
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WOS记录号WOS:000292912900020
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被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/30325
专题中国科学院金属研究所
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W. L. Feng,L. C. Pu,X. Z. Yang,et al. An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor[J]. Journal of Magnetism and Magnetic Materials,2011,323(22):2828-2830.
APA W. L. Feng,L. C. Pu,X. Z. Yang,&N. Hu.(2011).An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor.Journal of Magnetism and Magnetic Materials,323(22),2828-2830.
MLA W. L. Feng,et al."An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor".Journal of Magnetism and Magnetic Materials 323.22(2011):2828-2830.
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