An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor | |
W. L. Feng; L. C. Pu; X. Z. Yang; N. Hu | |
2011 | |
发表期刊 | Journal of Magnetism and Magnetic Materials
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ISSN | 0304-8853 |
卷号 | 323期号:22页码:2828-2830 |
摘要 | In this paper, the nickel site, optical spectra and electron paramagnetic resonance (EPR) g factor of nickel-zinc phosphate glasses have been studied by ligand-field theory. The orbital mixing effect between p and d orbits has been included in the calculation by two-spin-orbit parameter model. The present study shows that nickel occupies the tetrahedral zinc site with cubic symmetry in nickel-zinc phosphate glasses. Unlike the result of previous study that assigns nickel to an octahedral interstitial site, it is an optional explanation for nickel sites in nickel-zinc phosphate glasses by analysing the optical absorption spectra and EPR g factor. (C) 2011 Elsevier B.V. All rights reserved. |
部门归属 | [feng, w. l.; pu, l. c.; yang, x. z.; hu, n.] chongqing univ technol, dept appl phys, chongqing 400054, peoples r china. [feng, w. l.] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;feng, wl (reprint author), chongqing univ technol, dept appl phys, chongqing 400054, peoples r china;wenlinfeng@126.com |
关键词 | Electron Paramagnetic Resonance (Epr) Ligand Field Theory Local Lattice Structure Glasses Spin-hamiltonian Parameters Atomic Screening Constants Scf Functions Centers Crystal Ni++ |
URL | 查看原文 |
WOS记录号 | WOS:000292912900020 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/30325 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. L. Feng,L. C. Pu,X. Z. Yang,et al. An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor[J]. Journal of Magnetism and Magnetic Materials,2011,323(22):2828-2830. |
APA | W. L. Feng,L. C. Pu,X. Z. Yang,&N. Hu.(2011).An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor.Journal of Magnetism and Magnetic Materials,323(22),2828-2830. |
MLA | W. L. Feng,et al."An optional explanation for nickel sites of nickel-zinc phosphate glasses by their optical spectra and EPR g factor".Journal of Magnetism and Magnetic Materials 323.22(2011):2828-2830. |
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