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Influence of Zn on oxide films on Alloy 690 in borated and lithiated high temperature water
J. B. Huang; X. H. Liu; E. H. Han; X. Q. Wu
2011
发表期刊Corrosion Science
ISSN0010-938X
卷号53期号:10页码:3254-3261
摘要To clarify the corrosion control effect of Zn injection into hydrothermal environments, the oxide films on Alloy 690 in the deaerated borated and lithiated water have been investigated using potentiodynamic polarization curves, electrochemical impedance spectra at 300 degrees C and ex-situ X-ray photoelectron spectroscopy. With Zn injection in the solution, ZnCr(2)O(4) and ZnFe(2)O(4) were formed in the inner and outer layers of the oxide films on Alloy 690, respectively, through exchange reactions between Zn(2+) and Fe(2+)/Ni(2+). A simple model for oxide film structure change and the mechanism of corrosion inhibition by Zn injection is proposed and discussed. (C) 2011 Elsevier Ltd. All rights reserved.
部门归属[huang, junbo; liu, xiahe; han, en-hou; wu, xinqiang] chinese acad sci, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, inst met res, shenyang 110016, peoples r china.;han, eh (reprint author), chinese acad sci, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, inst met res, 62 wencui rd, shenyang 110016, peoples r china;ehhan@imr.ac.cn xqwu@imr.ac.cn
关键词Alloy Zn Eis Xps High Temperature Corrosion Ray Photoelectron-spectroscopy Radiation-field Buildup 25-300 Degrees-c Hydrogenated Water Corrosion Behavior Stainless-steel Passive Films Electrochemical Properties Pourbaix Diagrams Pitting Behavior
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WOS记录号WOS:000294396200025
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被引频次:69[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/30410
专题中国科学院金属研究所
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J. B. Huang,X. H. Liu,E. H. Han,et al. Influence of Zn on oxide films on Alloy 690 in borated and lithiated high temperature water[J]. Corrosion Science,2011,53(10):3254-3261.
APA J. B. Huang,X. H. Liu,E. H. Han,&X. Q. Wu.(2011).Influence of Zn on oxide films on Alloy 690 in borated and lithiated high temperature water.Corrosion Science,53(10),3254-3261.
MLA J. B. Huang,et al."Influence of Zn on oxide films on Alloy 690 in borated and lithiated high temperature water".Corrosion Science 53.10(2011):3254-3261.
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