Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water

IMR OpenIR

	Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water; Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water; Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water
	X. H. Liu; X. Q. Wu; E. H. Han
	2011 ; 2011 ; 2011
发表期刊	Corrosion Science ; Corrosion Science ; Corrosion Science
ISSN	0010-938X ; 0010-938X ; 0010-938X
卷号	53 期号:10 页码:3337-3345
摘要	The oxide film on 304 stainless steel exposed to the hydrothermal environments at 573.15 K up to 20 days without/with 10 ppb Zn injection has been investigated ex situ by X-ray photoelectron spectroscopy (XPS). ZnFe(2)O(4) and ZnCr(2)O(4) were found to be formed in the oxide film at the initial stage of immersion by substitution reaction between Zn(2+) and Fe(2+), and ZnCr(2)O(4) became dominant after long-term immersion. The calculations of potential-pH diagrams, solubilities and crystallographic features of spinels have been done to evaluate the oxide film structure and the inhibition mechanism caused by Zn injection. (C) 2011 Elsevier Ltd. All rights reserved.; The oxide film on 304 stainless steel exposed to the hydrothermal environments at 573.15 K up to 20 days without/with 10 ppb Zn injection has been investigated ex situ by X-ray photoelectron spectroscopy (XPS). ZnFe(2)O(4) and ZnCr(2)O(4) were found to be formed in the oxide film at the initial stage of immersion by substitution reaction between Zn(2+) and Fe(2+), and ZnCr(2)O(4) became dominant after long-term immersion. The calculations of potential-pH diagrams, solubilities and crystallographic features of spinels have been done to evaluate the oxide film structure and the inhibition mechanism caused by Zn injection. (C) 2011 Elsevier Ltd. All rights reserved.; The oxide film on 304 stainless steel exposed to the hydrothermal environments at 573.15 K up to 20 days without/with 10 ppb Zn injection has been investigated ex situ by X-ray photoelectron spectroscopy (XPS). ZnFe(2)O(4) and ZnCr(2)O(4) were found to be formed in the oxide film at the initial stage of immersion by substitution reaction between Zn(2+) and Fe(2+), and ZnCr(2)O(4) became dominant after long-term immersion. The calculations of potential-pH diagrams, solubilities and crystallographic features of spinels have been done to evaluate the oxide film structure and the inhibition mechanism caused by Zn injection. (C) 2011 Elsevier Ltd. All rights reserved.
部门归属	[liu, xiahe; wu, xinqiang; han, en-hou] chinese acad sci, inst met res, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, shenyang 110016, peoples r china.;wu, xq (reprint author), chinese acad sci, inst met res, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, 62 wencui rd, shenyang 110016, peoples r china;xqwu@imr.ac.cn ; [liu, xiahe; wu, xinqiang; han, en-hou] chinese acad sci, inst met res, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, shenyang 110016, peoples r china.;wu, xq (reprint author), chinese acad sci, inst met res, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, 62 wencui rd, shenyang 110016, peoples r china;xqwu@imr.ac.cn ; [liu, xiahe; wu, xinqiang; han, en-hou] chinese acad sci, inst met res, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, shenyang 110016, peoples r china.;wu, xq (reprint author), chinese acad sci, inst met res, state key lab corros & protect, liaoning key lab safety & assessment tech nucl ma, 62 wencui rd, shenyang 110016, peoples r china;xqwu@imr.ac.cn
关键词	Stainless Steel Stainless Steel Stainless Steel Zinc Zinc Zinc Xps Xps Xps Oxidation Oxidation Oxidation Thermodynamic Diagrams Thermodynamic Diagrams Thermodynamic Diagrams Corrosion Behavior Corrosion Behavior Corrosion Behavior Hydrogenated Water Hydrogenated Water Hydrogenated Water Stainless-steel Stainless-steel Stainless-steel Cation Cation Cation Distributions Distributions Distributions Tetrahedral Sites Tetrahedral Sites Tetrahedral Sites Simple Spinels Simple Spinels Simple Spinels Passive Films Passive Films Passive Films Zinc Zinc Zinc Xps Xps Xps Thermodynamics Thermodynamics Thermodynamics
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WOS记录号	WOS:000294396200035 ; WOS:000294396200035 ; WOS:000294396200035
引用统计	被引频次：74[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/30550
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	X. H. Liu,X. Q. Wu,E. H. Han. Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water, Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water, Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water[J]. Corrosion Science, Corrosion Science, Corrosion Science,2011, 2011, 2011,53, 53, 53(10):3337-3345, 3337-3345, 3337-3345.
APA	X. H. Liu,X. Q. Wu,&E. H. Han.(2011).Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water.Corrosion Science,53(10),3337-3345.
MLA	X. H. Liu,et al."Influence of Zn injection on characteristics of oxide film on 304 stainless steel in borated and lithiated high temperature water".Corrosion Science 53.10(2011):3337-3345.