An ultrafine-grained (UFG) Ni(3)Al was fabricated by annealing an electrodeposited Ni-Al composite in vacuum at 600 degrees C for 2 h. The UFG Ni(3)Al, compared to a compositional-similar but coarse-grained (CG) alloy prepared by arc-melting, exhibited a greatly increased cyclic oxidation resistance at 900 degrees C. Microstructural investigation showed that the CG alloy grew a scale with a high susceptibility to buckling and cracking because of the formation of large voids at the scale/metal interface, but that the UFG alloy grew an adherent scale, because its typical structure prevented the formation of the interface void during oxidation. (C) 2011 Elsevier Ltd. All rights reserved.
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[peng, x.; li, m.; wang, f.] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;peng, x (reprint author), chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china;xpeng@imr.ac.cn
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