Recent Progress on the Growth Mechanism of Carbon Nanotubes: A Review

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	Recent Progress on the Growth Mechanism of Carbon Nanotubes: A Review
	J. P. Tessonnier; D. S. Su
	2011
发表期刊	Chemsuschem
ISSN	1864-5631
卷号	4 期号:7 页码:824-847
摘要	Tremendous progress has been achieved during the past 20 years on not only improving the yields of carbon nanotubes and move progressively towards their mass production, but also on gaining a profound fundamental understanding of the nucleation and the growth processes. Parameters that influence the yield but also the quality (e. g., microstructure, homogeneity within a batch) are better understood. The influence of the carbon precursor, the reaction conditions, the presence of a catalyst, the chemical and physical status of the latter, and other factors have been extensively studied. The purpose of the present Review is not to list all the experiments reported in the literature, but rather to identify trends and provide a comprehensive summary on the role of selected parameters. The role of the catalyst occupies a central place in this Review as a careful control of the metal particle size, particle dispersion on the support, the metastable phase formed under reaction conditions, its possible reconstruction, and faceting strongly influence the diameter of the carbon nanotubes, their structure (number of walls, graphene sheet orientation, chirality), their alignment, and the yield. The identified trends will be compared with recent observations on the growth of graphene. Recent results on metal-free catalysts will be analyzed from a different perspective.
部门归属	[tessonnier, jean-philippe; su, dang sheng] max planck soc, fritz haber inst, d-14195 berlin, germany. [su, dang sheng] chinese acad sci, inst met res, shenyang 110016, peoples r china.;su, ds (reprint author), max planck soc, fritz haber inst, faradayweg 4-6, d-14195 berlin, germany;dangsheng@fhi-berlin.mpg.de
关键词	Carbon Catalysis Growth Mechanism Nanoparticles Nanotubes Chemical-vapor-deposition Oxidative Dehydrogenation Reactions Electrochemical Energy-storage Layered Double Hydroxides Single-walled Nanotubes Iron Catalyst Particles Large-scale Synthesis Filamentous Carbon Metal-catalysts Arc-discharge
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WOS记录号	WOS:000293594300002
引用统计	被引频次：315[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/30709
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	J. P. Tessonnier,D. S. Su. Recent Progress on the Growth Mechanism of Carbon Nanotubes: A Review[J]. Chemsuschem,2011,4(7):824-847.
APA	J. P. Tessonnier,&D. S. Su.(2011).Recent Progress on the Growth Mechanism of Carbon Nanotubes: A Review.Chemsuschem,4(7),824-847.
MLA	J. P. Tessonnier,et al."Recent Progress on the Growth Mechanism of Carbon Nanotubes: A Review".Chemsuschem 4.7(2011):824-847.