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PbO(2)-SnO(2) composite anode with interconnected structure for the electrochemical incineration of phenol
L. Wei; X. H. Mao; A. Lin; F. X. Gan
2011
发表期刊Russian Journal of Electrochemistry
ISSN1023-1935
卷号47期号:12页码:1394-1398
摘要A PbO(2)-SnO(2) composite anode with interconnected structure is prepared for organics electro-incineration through a two-step method, thermal-decomposition process and subsequent low-current density electrodeposition process. The element mapping, together with the impedance spectra of the composite electrode, confirms that an interconnected architecture of SnO(2) and PbO(2) grains, instead of a lamellar structure, was obtained on the Ti substrate. A lower electrodeposition current density (a parts per thousand currency sign10 mA cm(-2)) is very crucial for the formation of a porous surface and an interconnected architecture of two oxides inside. The asprepared electrode exhibits an enhanced electrocatalytic activity on the mineralization of phenol and a long service life due to the interconnected architecture, which helps to utilize the merits of these two metal oxides simultaneously. This two-step method also provides us a novel and facile way to fabricate a series of composite material such as oxide-oxide, oxide-metal composite electrodes.
部门归属[wei, lin; mao, xuhui; lin, an; gan, fuxing] wuhan univ, sch resource & environm sci, wuhan 430072, peoples r china. [gan, fuxing] state key lab corros & protect met, shenyang 110016, peoples r china.;mao, xh (reprint author), wuhan univ, sch resource & environm sci, wuhan 430072, peoples r china;clab@whu.edu.cn
关键词Interconnected Structure Lead Dioxide Tin Dioxide Electrochemical Incineration Waste-water Treatment Lead Dioxide Fuel-cell Degradation Oxidation Electrodes Catalyst Pbo2 Deposition Reduction
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/30768
专题中国科学院金属研究所
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L. Wei,X. H. Mao,A. Lin,et al. PbO(2)-SnO(2) composite anode with interconnected structure for the electrochemical incineration of phenol[J]. Russian Journal of Electrochemistry,2011,47(12):1394-1398.
APA L. Wei,X. H. Mao,A. Lin,&F. X. Gan.(2011).PbO(2)-SnO(2) composite anode with interconnected structure for the electrochemical incineration of phenol.Russian Journal of Electrochemistry,47(12),1394-1398.
MLA L. Wei,et al."PbO(2)-SnO(2) composite anode with interconnected structure for the electrochemical incineration of phenol".Russian Journal of Electrochemistry 47.12(2011):1394-1398.
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