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A Comparative Study of the Corrosion Behavior of Three Stainless Steels in an Eutectic (Li,Na,K)(2)CO(3) Melt with and without (Na,K)Cl Additives at 973K in Air
C. L. Zeng; Y. Liu
2011
Source PublicationHigh Temperature Materials and Processes
ISSN0334-6455
Volume30Issue:1-2Pages:161-169
AbstractThe ternary carbonate eutectic mixture of Li(2)CO(3), K(2)CO(3) and Na(2)CO(3) as a heat transfer and storage medium has excellent thermophysical properties, but with high viscidity as compared with some other inorganic salts such as chlorides and nitrates. The addition of chlorides or fluorides to molten carbonates may improve their fluidity, but possibly making the melt become more corrosive. In this study, the corrosion behavior of type 304, 310 and 316 stainless steels in an eutectic (Li,Na,K)(2)CO(3) melt with and without an eutectic mixture of NaCl and KCl at 973K in air have been examined. The experimental results indicated that 310 steel shows a much better corrosion resistance in molten carbonates than both 304 and 316 steels, due to the formation of a continuous LiCrO(2) scale. The addition of chlorides to carbonates melt accelerated the corrosion of the steels, especially 310 steel, producing scales with more porosity.
description.department[zeng, c. l.; liu, y.] chinese acad sci, state key lab corros & protect, inst met res, shenyang 110016, peoples r china.;zeng, cl (reprint author), chinese acad sci, state key lab corros & protect, inst met res, 62 wencui rd, shenyang 110016, peoples r china;clzeng@imr.ac.cn
KeywordStainless Steels (Li (Na Na k)Cl k)(2)Co(3) Molten Salts Corrosion Latent-heat-storage Potassium Carbonates Lithium Sodium
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Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/30861
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
C. L. Zeng,Y. Liu. A Comparative Study of the Corrosion Behavior of Three Stainless Steels in an Eutectic (Li,Na,K)(2)CO(3) Melt with and without (Na,K)Cl Additives at 973K in Air[J]. High Temperature Materials and Processes,2011,30(1-2):161-169.
APA C. L. Zeng,&Y. Liu.(2011).A Comparative Study of the Corrosion Behavior of Three Stainless Steels in an Eutectic (Li,Na,K)(2)CO(3) Melt with and without (Na,K)Cl Additives at 973K in Air.High Temperature Materials and Processes,30(1-2),161-169.
MLA C. L. Zeng,et al."A Comparative Study of the Corrosion Behavior of Three Stainless Steels in an Eutectic (Li,Na,K)(2)CO(3) Melt with and without (Na,K)Cl Additives at 973K in Air".High Temperature Materials and Processes 30.1-2(2011):161-169.
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