Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate

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	Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate
	R. P. Chai; X. Y. Kuang; M. L. Duan; C. X. Zhang
	2010
发表期刊	Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
ISSN	1386-1425
卷号	77 期号:1 页码:253-257
摘要	The optical and EPR spectra of octahedral Er(3+) center in LiNbO(3) have been studied by diagonalizing 364 x 364 complete energy matrices. The new set of crystal-field parameters that can well account for the Stark levels and EPR parameters have been obtained for Er(3+) ions in LiNbO(3). Simultaneously, by simulating the most reliable six-order parameter B(60) obtained, we have presented the evidence that the Er(3+) ions do not occupy the actual Li(+) site, but have a displacement along the C(3)-axis away from the Li(+) center by about 0.0454 nm. The conclusion is well in accord with that drawn by earlier workers. (c) 2010 Elsevier B.V. All rights reserved.
部门归属	[chai, rui-peng; kuang, xiao-yu; duan, mei-ling; zhang, cai-xia] sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. [kuang, xiao-yu] acad sinica, int ctr mat phys, shenyang 110016, peoples r china.;kuang, xy (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;scu_crp@163.com
关键词	Epr Parameters Defect Structure Complete Energy Matrices Linbo3 Single-crystals Wave-guide Lasers 24 Degrees c Superposition Model Local-structure Ions Sites Spectroscopy Diffraction Fields
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31014
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	R. P. Chai,X. Y. Kuang,M. L. Duan,et al. Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2010,77(1):253-257.
APA	R. P. Chai,X. Y. Kuang,M. L. Duan,&C. X. Zhang.(2010).Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,77(1),253-257.
MLA	R. P. Chai,et al."Theoretical studies of EPR spectra and defect structure for Er(3+) center in lithium niobate".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 77.1(2010):253-257.