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Improved hydrogen storage properties of LiBH(4) by mechanical milling with various carbon additives
Z. Z. Fang; X. D. Kang; P. Wang
2010
发表期刊International Journal of Hydrogen Energy
ISSN0360-3199
卷号35期号:15页码:8247-8252
摘要Various LiBH(4)/carbon (graphite (G), purified single-walled carbon nanotubes (SWNTs) and activated carbon (AC)) composites were prepared by mechanical milling method and further examined with respect to their hydrogen storage properties. It was found that all the carbon additives can improve the H-exchange kinetics and H-capacity of LiBH(4) to some extents. Compared with G, SWNTs and AC exhibited better promoting effect on the hydrogen storage properties of LiBH(4). Based on combined property/phase/structure analysis results, the promoting effect of the carbon additives was largely attributed to their heterogeneous nucleation and micro-confinement effect on the reversible dehydrogenation of LiBH(4). (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
部门归属[fang, zhan-zhao; kang, xiang-dong; wang, ping] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;wang, p (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china;pingwang@imr.ac.cn
关键词Lithium Borohydride Carbon Additive Mechanical Milling Hydrogen Storage Arc-discharge Method Lithium Borohydride Nanotubes Performances Composite Hydrides
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31092
专题中国科学院金属研究所
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Z. Z. Fang,X. D. Kang,P. Wang. Improved hydrogen storage properties of LiBH(4) by mechanical milling with various carbon additives[J]. International Journal of Hydrogen Energy,2010,35(15):8247-8252.
APA Z. Z. Fang,X. D. Kang,&P. Wang.(2010).Improved hydrogen storage properties of LiBH(4) by mechanical milling with various carbon additives.International Journal of Hydrogen Energy,35(15),8247-8252.
MLA Z. Z. Fang,et al."Improved hydrogen storage properties of LiBH(4) by mechanical milling with various carbon additives".International Journal of Hydrogen Energy 35.15(2010):8247-8252.
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