Effect of non-stoichiometry on hydrogen storage properties of La(Ni(3.8)Al(1.0)Mn(0.2))(x) alloys

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	Effect of non-stoichiometry on hydrogen storage properties of La(Ni(3.8)Al(1.0)Mn(0.2))(x) alloys
	S. L. Li; P. Wang; W. Chen; G. Luo; D. M. Chen; K. Yang
	2010
发表期刊	International Journal of Hydrogen Energy
ISSN	0360-3199
卷号	35 期号:8 页码:3537-3545
摘要	The La(Ni(3.8)Al(1.0)Mn(0.2))(x) (x= 0.94, 0.96, 0.98, 1.0) hydrogen storage alloys have been investigated to examine the effect of non-stoichiometry on the crystal structure, activation performance, hydrogen absorption/desorption properties and cycle life. It was found that for the stoichiometric compound, only single phase with CaCu(5) type structure exists. However, for B-poor compounds of AB(5) alloys, there is a principal CaCu(5) type phase with a small amount of second phase and the amount of second phase increased with decreasing x when x >= 0.96 and reached a maximum when x = 0.96. The activation becomes harder with decreasing x until x = 0.96 and easier when x decreased to 0.94. The plateau pressure increased and the hydrogen uptake capacity decreased with decreasing x when x >= 0.96, and then decreased and increased, respectively, when x further decreased to 0.94. Both the change in the lattice strain which could be estimated by FWHM (full width at half maximum) and the degree of slope factor S(f) in the alloys show the same trend with the change of x, exhibiting a maximum at x = 0.96. The Delta H decreased with decreasing x when x >= 0.96 and then increased when x = 0.94 and it was found that the larger the cell volume, the larger the absolute value of the enthalpy. The pulverization resistance of the alloys was greatly improved by the non-stoichiometric. The kinetics of the alloys was very fast and almost not influenced by the change of non-stoichiometric x. After 300 absorption/desorption cycles, the hydrogen uptake capacity of the stoichiometric and non-stoichiometric alloys almost kept the same, but the particle size decreased greatly. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
部门归属	[li, s. l.; chen, w.; luo, g.; chen, d. m.; yang, k.] chinese acad sci, inst met res, shenyang 110016, peoples r china. [li, s. l.; chen, w.; luo, g.] chinese acad sci, grad sch, beijing 100049, peoples r china. [wang, p.] 404 ltd co, china natl nucl corp, lanzhou 732850, peoples r china.;chen, dm (reprint author), chinese acad sci, inst met res, shenyang 110016, peoples r china;demin.chen.1@imr.ac.cn
关键词	Metal Hydride Hydrogen Absorbing Materials Gas-solid Reactions Thermodynamic Properties Electrochemical Cycling Stability Hydride-forming Compounds Thermodynamic Parameters Lani5-based Alloys Crystal-structure Rare-earth Ni Substitution System Co
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WOS记录号	WOS:000277463600041
引用统计	被引频次：24[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31234
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	S. L. Li,P. Wang,W. Chen,et al. Effect of non-stoichiometry on hydrogen storage properties of La(Ni(3.8)Al(1.0)Mn(0.2))(x) alloys[J]. International Journal of Hydrogen Energy,2010,35(8):3537-3545.
APA	S. L. Li,P. Wang,W. Chen,G. Luo,D. M. Chen,&K. Yang.(2010).Effect of non-stoichiometry on hydrogen storage properties of La(Ni(3.8)Al(1.0)Mn(0.2))(x) alloys.International Journal of Hydrogen Energy,35(8),3537-3545.
MLA	S. L. Li,et al."Effect of non-stoichiometry on hydrogen storage properties of La(Ni(3.8)Al(1.0)Mn(0.2))(x) alloys".International Journal of Hydrogen Energy 35.8(2010):3537-3545.