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Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4)
G. Q. Liu; L. Wen; G. Y. Liu; Y. W. Tian
2010
发表期刊Journal of Alloys and Compounds
ISSN0925-8388
卷号501期号:2页码:233-235
摘要The spinel compound LiCr(0.1)Ni(0.4)Mn(1.5)O(4) is synthesized by a sol-gel method In this synthesizing process, Li(CH(3)COO)2H(2)O, Ni(CH(3)COO)(2) 4H(2)O, Mn(CH(3)COO)(2) 4H(2)O and Cr(NO(3))(3) 9H(2)O are used as reactants, and malic acid as chelating agent The reaction takes place at 900 degrees C for 8 h. The electrochemical performances of the as-prepared sample are measured at different current rates In the range of 3.5-5.0 V, its discharge capacities are 141, 125 and 95 mAh g(-1) at 0.5, 1 and 5C, respectively. Based on cycle voltammerry results, the diffusion coefficient of Li(+) is calculated as 6.75 x 10(-10) cm(2) s(-1) at 407 V in oxidation process. (C) 2010 Elsevier B V. All rights reserved
部门归属[liu, g. q.; liu, g. y.; tian, y. w.] northeastern univ, sch met & mat, shenyang 110004, peoples r china. [wen, l.] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;liu, gq (reprint author), northeastern univ, sch met & mat, shenyang 110004, peoples r china
关键词Licr(0.1)Ni(0.4)Mn(1.5)o(4) Li-ion Batteries Cathode Material Properties Rate Capability Cathode Materials Electrochemical Characteristics Lini0.5mn1.5o4 Batteries Electrode Substitution Performance Mn
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31285
专题中国科学院金属研究所
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GB/T 7714
G. Q. Liu,L. Wen,G. Y. Liu,et al. Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4)[J]. Journal of Alloys and Compounds,2010,501(2):233-235.
APA G. Q. Liu,L. Wen,G. Y. Liu,&Y. W. Tian.(2010).Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4).Journal of Alloys and Compounds,501(2),233-235.
MLA G. Q. Liu,et al."Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4)".Journal of Alloys and Compounds 501.2(2010):233-235.
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