Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4) | |
G. Q. Liu; L. Wen; G. Y. Liu; Y. W. Tian | |
2010 | |
发表期刊 | Journal of Alloys and Compounds
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ISSN | 0925-8388 |
卷号 | 501期号:2页码:233-235 |
摘要 | The spinel compound LiCr(0.1)Ni(0.4)Mn(1.5)O(4) is synthesized by a sol-gel method In this synthesizing process, Li(CH(3)COO)2H(2)O, Ni(CH(3)COO)(2) 4H(2)O, Mn(CH(3)COO)(2) 4H(2)O and Cr(NO(3))(3) 9H(2)O are used as reactants, and malic acid as chelating agent The reaction takes place at 900 degrees C for 8 h. The electrochemical performances of the as-prepared sample are measured at different current rates In the range of 3.5-5.0 V, its discharge capacities are 141, 125 and 95 mAh g(-1) at 0.5, 1 and 5C, respectively. Based on cycle voltammerry results, the diffusion coefficient of Li(+) is calculated as 6.75 x 10(-10) cm(2) s(-1) at 407 V in oxidation process. (C) 2010 Elsevier B V. All rights reserved |
部门归属 | [liu, g. q.; liu, g. y.; tian, y. w.] northeastern univ, sch met & mat, shenyang 110004, peoples r china. [wen, l.] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;liu, gq (reprint author), northeastern univ, sch met & mat, shenyang 110004, peoples r china |
关键词 | Licr(0.1)Ni(0.4)Mn(1.5)o(4) Li-ion Batteries Cathode Material Properties Rate Capability Cathode Materials Electrochemical Characteristics Lini0.5mn1.5o4 Batteries Electrode Substitution Performance Mn |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/31285 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | G. Q. Liu,L. Wen,G. Y. Liu,et al. Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4)[J]. Journal of Alloys and Compounds,2010,501(2):233-235. |
APA | G. Q. Liu,L. Wen,G. Y. Liu,&Y. W. Tian.(2010).Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4).Journal of Alloys and Compounds,501(2),233-235. |
MLA | G. Q. Liu,et al."Rate capability of spinel LiCr(0.1)Ni(0.4)Mn(1.5)O(4)".Journal of Alloys and Compounds 501.2(2010):233-235. |
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