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Free-Standing Highly Conductive Transparent Ultrathin Single-Walled Carbon Nanotube Films
Q. F. Liu; T. Fujigaya; H. M. Cheng; N. Nakashima
2010
发表期刊Journal of the American Chemical Society
ISSN0002-7863
卷号132期号:46页码:16581-16586
摘要Transparent and conductive single-walled carbon nanotube (SWNT) films are of great importance to a number of applications such as optical and electronic devices. Here, we describe a simple approach for preparing free-standing highly conductive transparent SWNT films with a 20-150 nm thickness by spray coating from surfactant-dispersed aqueous solutions of SWNTs synthesized by an improved floating-catalyst growth method. After the HNO(3) treatment, dipping the SWNT films supporting on glass substrates in water resulted in a quick and nondestructive self-release to form free-standing ultrathin SWNT films on the water surface. The obtained films have sufficiently high transmittance (i.e., 95%), a very low sheet resistance (i.e., similar to 120 Omega/sq) and a small average surface roughness (i.e., similar to 3.5 nm for a displayed 10 x 10 mu m area). Furthermore, the floating SWNT films on the water surface were easily transferred to any substrates of interest, without intense mechanical and chemical treatments, to preserve their original sizes and network structures. For example, the transferred SWNT films on poly(ethylene terephthalate) films are mechanically flexible, which is a great advantage over conventional indium-tin oxide (ITO) and therefore strongly promise to be "post ITO" or many applications.
部门归属[liu, qingfeng; fujigaya, tsuyohiko; nakashima, naotoshi] kyushu univ, dept appl chem, grad sch engn, nishi ku, fukuoka 8190395, japan. [cheng, hui-ming] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china. [nakashima, naotoshi] japan sci & technol agcy jst, crest, chiyoda ku, tokyo 1020075, japan.;nakashima, n (reprint author), kyushu univ, dept appl chem, grad sch engn, nishi ku, 744 motooka, fukuoka 8190395, japan;nakashima-tcm@mail.cstm.kyushu-u.ac.jp
关键词Thin-films Honeycomb Structures Sheets Photovoltaics Hydrocarbons Fabrication Transistors Electrodes Networks Coatings
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WOS记录号WOS:000284792000049
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被引频次:80[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31306
专题中国科学院金属研究所
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Q. F. Liu,T. Fujigaya,H. M. Cheng,et al. Free-Standing Highly Conductive Transparent Ultrathin Single-Walled Carbon Nanotube Films[J]. Journal of the American Chemical Society,2010,132(46):16581-16586.
APA Q. F. Liu,T. Fujigaya,H. M. Cheng,&N. Nakashima.(2010).Free-Standing Highly Conductive Transparent Ultrathin Single-Walled Carbon Nanotube Films.Journal of the American Chemical Society,132(46),16581-16586.
MLA Q. F. Liu,et al."Free-Standing Highly Conductive Transparent Ultrathin Single-Walled Carbon Nanotube Films".Journal of the American Chemical Society 132.46(2010):16581-16586.
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