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Effect of electrodeposition parameters on the hydrogen permeation during Cu-Sn alloy electrodeposition
G. Z. Meng; F. L. Sun; S. J. Wang; Y. W. Shao; T. Zhang; F. H. Wang
2010
发表期刊Electrochimica Acta
ISSN0013-4686
卷号55期号:7页码:2238-2245
摘要The Cu-Sn alloy coatings were synthesized on 27SiMn steel by direct current (DC), pulse current (PC) and pulse reverse current (PRC) electrodeposition techniques from pyrophosphate-based electrolyte. The hydrogen permeation behaviors during the electrodeposition by different techniques were investigated using Devanathan-Stachurski method. The results demonstrated that the hydrogen permeation amount of different electrodeposition techniques decreased in the order: DC > PC > PRC. Frequency and duty cycle have great effect on the sub-surface concentration C(o) of atomic hydrogen and hydrogen permeation amount. The minimum of hydrogen permeation amount was observed at the frequency of 1000 Hz or 2500 Hz and the duty cycle of 40%. It indicates that the amount of permeated hydrogen in the steel during deposition can be reduced due to the decrease of C(o) by PC and PRC methods. (C) 2009 Elsevier Ltd. All rights reserved.
部门归属[meng, guozhe] harbin engn univ, corros & protect lab, coll mat sci & chem eng, key lab superlight mat & surface technol,minist e, harbin 150001, heilongjiang pr, peoples r china. [meng, guozhe; shao, yawei; zhang, tao; wang, fuhui] chinese acad sci, met res inst, state key lab corros & protect, shenyang 110016, peoples r china.;meng, gz (reprint author), harbin engn univ, corros & protect lab, coll mat sci & chem eng, key lab superlight mat & surface technol,minist e, nantong st 145, harbin 150001, heilongjiang pr, peoples r china;mengguozhe@hrbeu.edu.cn
关键词Cu-sn Alloy Coating Hydrogen Blister Hydrogen Permeation Hydrogen Diffusivity Pulse Current Electrodeposition Pyrophosphate-based Electrolytes Different Temperatures Ph-microscopy Carbon-steel Thin-films Iron Electromigration Deposition Metals Interconnects
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WOS记录号WOS:000275540100004
引用统计
被引频次:29[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31380
专题中国科学院金属研究所
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GB/T 7714
G. Z. Meng,F. L. Sun,S. J. Wang,et al. Effect of electrodeposition parameters on the hydrogen permeation during Cu-Sn alloy electrodeposition[J]. Electrochimica Acta,2010,55(7):2238-2245.
APA G. Z. Meng,F. L. Sun,S. J. Wang,Y. W. Shao,T. Zhang,&F. H. Wang.(2010).Effect of electrodeposition parameters on the hydrogen permeation during Cu-Sn alloy electrodeposition.Electrochimica Acta,55(7),2238-2245.
MLA G. Z. Meng,et al."Effect of electrodeposition parameters on the hydrogen permeation during Cu-Sn alloy electrodeposition".Electrochimica Acta 55.7(2010):2238-2245.
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