Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H(2)SO(4): Synergistic effect of iodide ions | |
S. A. Umoren; Y. Li; F. H. Wang | |
2010 | |
发表期刊 | Corrosion Science
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ISSN | 0010-938X |
卷号 | 52期号:5页码:1777-1786 |
摘要 | Corrosion inhibition and adsorption behaviour for pure iron in 0.5 M H(2)SO(4) by polyacrylamide (PA) were investigated using electrochemical techniques. The effect of iodide ion additives was also studied. It was found that inhibition efficiency increased with PA concentration. Corrosion inhibition was afforded by adsorption of PA onto the metal following El-Awady kinetic thermodynamic adsorption isotherm model via chemisorption mechanism. A mixed inhibition mechanism is proposed for the inhibitive effects of PA as revealed by potentiodynamic polarization technique. A synergistic effect was observed between PA and KI as evident from the values of synergism parameter found to be greater than unity. (C) 2010 Elsevier Ltd. All rights reserved. |
部门归属 | [umoren, s. a.; li, y.; wang, f. h.] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. [umoren, s. a.] univ uyo, fac sci, dept chem, uyo, nigeria.;li, y (reprint author), chinese acad sci, inst met res, state key lab corros & protect, 62 wencui rd, shenyang 110016, peoples r china;yiling@imr.ac.cn |
关键词 | Iron Polyacrylamide Iodide Ion Adsorption Corrosion Inhibition Synergism Cold-rolled Steel Hydrochloric-acid Solution m Hcl Solution Mild-steel Halide-ions Organic-compounds Sulfuric-acid Weight-loss Aluminum Media |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/31482 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | S. A. Umoren,Y. Li,F. H. Wang. Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H(2)SO(4): Synergistic effect of iodide ions[J]. Corrosion Science,2010,52(5):1777-1786. |
APA | S. A. Umoren,Y. Li,&F. H. Wang.(2010).Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H(2)SO(4): Synergistic effect of iodide ions.Corrosion Science,52(5),1777-1786. |
MLA | S. A. Umoren,et al."Electrochemical study of corrosion inhibition and adsorption behaviour for pure iron by polyacrylamide in H(2)SO(4): Synergistic effect of iodide ions".Corrosion Science 52.5(2010):1777-1786. |
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