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Thermal and Electrical Conductivities of the Graphitized Carbon Nanotube/poly (methyl methacrylate) Composites Based on Weak Nanotube-polymer Interactions
Y. Zeng; L. Zhao; P. F. Liu; J. H. Du; C. Liu
2010
发表期刊Chemical Journal of Chinese Universities-Chinese
ISSN0251-0790
卷号31期号:6页码:1263-1267
摘要Electrical and thermal conductivities of carbon nanotube (CNT)/polymer composites are greatly hindered by polymer-wrapping around CNTs due to high surface energy of CNTs. The graphitized multi-walled CNTs filled poly(methyl methacrylate) (PMMA) were investigated on the basis of surface physical chemistry and wetting thermodynamics. The electrical and thermal conductivities of the graphitized CNT/PMMA composites were measured to evaluate enhancing affects of the graphitized CNTs. The graphitized CNT/PMMA composites exhibit high electrical conductivity and a low percolation threshold of is 0.8% (mass fraction), and the thermal conductivity of the composites with 3% (mass fraction) increases by 193% in comparison with that of the neat PMMA, which is due to the integrated microstructures of the graphitized CNTs, weak CNT-PMMA interactions, low contact resistance between CNTs, and efficient conducting CNT-networks. We suggest that high-performance composites can be designed and fabricated by fully considering the surface energy of components and the filler-polymer interactions.
部门归属[zeng you; zhao long; liu peng-fei] shenyang jianzhu univ, sch mat sci & engn, shenyang 110168, peoples r china. [zhao long; liu peng-fei; du jin-hong; liu chang] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;zeng, y (reprint author), shenyang jianzhu univ, sch mat sci & engn, shenyang 110168, peoples r china;zengyou@sjzu.edu.cn
关键词Carbon Nanotube Weak Interaction Poly (Methyl Methacrylate) Composite Thermal And Electrical Conductivity Dispersion Transport Stability
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WOS记录号WOS:000279304500040
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31675
专题中国科学院金属研究所
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Y. Zeng,L. Zhao,P. F. Liu,et al. Thermal and Electrical Conductivities of the Graphitized Carbon Nanotube/poly (methyl methacrylate) Composites Based on Weak Nanotube-polymer Interactions[J]. Chemical Journal of Chinese Universities-Chinese,2010,31(6):1263-1267.
APA Y. Zeng,L. Zhao,P. F. Liu,J. H. Du,&C. Liu.(2010).Thermal and Electrical Conductivities of the Graphitized Carbon Nanotube/poly (methyl methacrylate) Composites Based on Weak Nanotube-polymer Interactions.Chemical Journal of Chinese Universities-Chinese,31(6),1263-1267.
MLA Y. Zeng,et al."Thermal and Electrical Conductivities of the Graphitized Carbon Nanotube/poly (methyl methacrylate) Composites Based on Weak Nanotube-polymer Interactions".Chemical Journal of Chinese Universities-Chinese 31.6(2010):1263-1267.
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