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Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO(3)
X. Q. Zhang; Y. Sui; X. J. Wang; Y. Wang; Z. Wang
2010
发表期刊Journal of Alloys and Compounds
ISSN0925-8388
卷号507期号:1页码:157-161
摘要Single-phase Bil(1-x)Eu(x)FeO(3) (0 <= x <= 0.3) multiferroic ceramics were prepared to study the effects of Eu substitution on their crystal structure and ferroelectromagnetic behavior. X-ray diffraction studies revealed a sequence of the composition-driven structural phase transitions R3c -> Pn2(1)alpha (occurs at x = 0.2). Magnetic measurements revealed that Eu substitution can effectively induce the appearance of the spontaneous magnetization, which was significantly enhanced upon the composition-driven transition from a rhombohedral to an orthorhombic phase. The leakage current was found to be reduced on increased Eu concentration. The electric hysteresis loops were obtained in the Bi(1-x)Eu(x)FeO(3) ceramics, but the loops were not really saturated. The magnetoelectric coupling in Eu-doped BiFeO(3) was estimated by the changes in the dielectric constant with an external magnetic filed. (C) 2010 Elsevier B.V. All rights reserved.
部门归属[zhang, xingquan; sui, yu; wang, xianjie; wang, zhu] harbin inst technol, ctr condensed matter sci & technol, dept phys, harbin 150001, peoples r china. [sui, yu] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. [wang, yang] nanyang technol univ, div phys & appl phys, sch phys & math sci, singapore 637371, singapore.;sui, y (reprint author), harbin inst technol, ctr condensed matter sci & technol, dept phys, pob 3025,sci pk, harbin 150001, peoples r china;suiyu@hit.edu.cn
关键词Multiferroic Bifeo(3) Substitution Magnetoelectric Coupling Magnetic-properties Ceramics Phase Polarization State
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/31727
专题中国科学院金属研究所
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X. Q. Zhang,Y. Sui,X. J. Wang,et al. Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO(3)[J]. Journal of Alloys and Compounds,2010,507(1):157-161.
APA X. Q. Zhang,Y. Sui,X. J. Wang,Y. Wang,&Z. Wang.(2010).Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO(3).Journal of Alloys and Compounds,507(1),157-161.
MLA X. Q. Zhang,et al."Effect of Eu substitution on the crystal structure and multiferroic properties of BiFeO(3)".Journal of Alloys and Compounds 507.1(2010):157-161.
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