The temperature dependence of magnetic properties for cobalt ferrite nanoparticles by the hydrothermal method | |
Y. Zhang; Y. Liu; C. L. Fei; Z. Yang; Z. H. Lu; R. Xiong; D. Yin; J. Shi | |
2010 | |
发表期刊 | Journal of Applied Physics
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ISSN | 0021-8979 |
卷号 | 108期号:8 |
摘要 | Cobalt ferrite nanoparticles were synthesized via the hydrothermal route with the addition of trisodium citrate dihydrate (Na(3)CA center dot 2H(2)O). The characterizations including x-ray diffraction (XRD) and transmission electron microscope showed that the products of this hydrothermal reaction are composed of cobalt ferrite nanocrystallite and a small amount of FeOOH, and the average crystallite size of the nanoparticles is 7.6 +/- 0.3 nm by XRD. The magnetic measurements revealed the temperature-dependent magnetic properties: The superparamagnetism occurs above 380 K due to the overcoming of energy barrier for the flip of spins, which arises from the magnetocrystalline anisotropy energy and the interparticle interactions due to the aggregation of the nanoparticles; a frozen spin-glasslike state was observed below 20 K, which is accompanied with the decrease in coercivity and high-field paramagnetic susceptibility, as well as the enhancement of saturated magnetization and the effective magnetic anisotropy constant. (C) 2010 American Institute of Physics. [doi:10.1063/1.3499289] |
部门归属 | [zhang, yue; liu, yong; fei, chunlong; yang, zhi; xiong, rui; yin, di; shi, jing] wuhan univ, minist educ, key lab artificial micro & nanostruct, wuhan 430072, peoples r china. [zhang, yue; liu, yong; fei, chunlong; yang, zhi; xiong, rui; yin, di; shi, jing] wuhan univ, sch phys & technol, wuhan 430072, peoples r china. [lu, zhihong] wuhan univ sci & technol, sch met & mat, wuhan 430072, peoples r china. [xiong, rui; shi, jing] wuhan univ, hubei key lab organ & polymer optoelect mat, wuhan 430072, peoples r china. [shi, jing] acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;zhang, y (reprint author), wuhan univ, minist educ, key lab artificial micro & nanostruct, wuhan 430072, peoples r china;yindi1975@163.com |
关键词 | Surface Spin Disorder Cofe2o4 Nanoparticles Mn Nanoparticles Mfe2o4 m Size Fe Nanocomposite Nanocrystals Particles Co |
URL | 查看原文 |
WOS记录号 | WOS:000283745100127 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/31731 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Y. Zhang,Y. Liu,C. L. Fei,et al. The temperature dependence of magnetic properties for cobalt ferrite nanoparticles by the hydrothermal method[J]. Journal of Applied Physics,2010,108(8). |
APA | Y. Zhang.,Y. Liu.,C. L. Fei.,Z. Yang.,Z. H. Lu.,...&J. Shi.(2010).The temperature dependence of magnetic properties for cobalt ferrite nanoparticles by the hydrothermal method.Journal of Applied Physics,108(8). |
MLA | Y. Zhang,et al."The temperature dependence of magnetic properties for cobalt ferrite nanoparticles by the hydrothermal method".Journal of Applied Physics 108.8(2010). |
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