In situ formation and rapid decomposition of Ti(BH(4))(3) by mechanical milling LiBH(4) with TiF(3)

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	In situ formation and rapid decomposition of Ti(BH(4))(3) by mechanical milling LiBH(4) with TiF(3)
	Z. Z. Fang; L. P. Ma; X. D. Kang; P. J. Wang; P. Wang; H. M. Cheng
	2009
发表期刊	Applied Physics Letters
ISSN	0003-6951
卷号	94 期号:4
摘要	Mechanically milled 3LiBH(4)/TiF(3) mixture can rapidly release over 5 wt % hydrogen at moderate temperatures (70-90 degrees C) without undesired gas impurity. Structure analyses results show that the favorable dehydrogenation performance of the material should be associated with the in situ formation and rapid decomposition of an intermediate titanium borohydride (Ti(BH(4))(3)). These findings demonstrated a viable chemical activation approach for promoting hydrogen release from the thermodynamically stable borohydrides. Particularly, it shows the potential of transition metal borohydrides for hydrogen storage applications.
部门归属	[fang, z. z.; ma, l. p.; kang, x. d.; wang, p. j.; wang, p.; cheng, h. m.] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;wang, p (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china;pingwang@imr.ac.cn
关键词	Boron Compounds Dissociation Hydrogen Storage Hydrogenation Lithium Compounds Milling Titanium Compounds Hydrogen Storage Lithium Borohydride 1st-principles Carbon Metal
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31893
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Z. Z. Fang,L. P. Ma,X. D. Kang,et al. In situ formation and rapid decomposition of Ti(BH(4))(3) by mechanical milling LiBH(4) with TiF(3)[J]. Applied Physics Letters,2009,94(4).
APA	Z. Z. Fang,L. P. Ma,X. D. Kang,P. J. Wang,P. Wang,&H. M. Cheng.(2009).In situ formation and rapid decomposition of Ti(BH(4))(3) by mechanical milling LiBH(4) with TiF(3).Applied Physics Letters,94(4).
MLA	Z. Z. Fang,et al."In situ formation and rapid decomposition of Ti(BH(4))(3) by mechanical milling LiBH(4) with TiF(3)".Applied Physics Letters 94.4(2009).